- (a) Applicability. All community and nontransient, non-community water systems shall comply with the requirements of this section regarding organic contaminants. For purposes of this section, systems using groundwater under the direct influence of surface water shall meet the organic sampling requirements given for surface water systems.
(b) Maximum contaminant levels (MCLs) for organic contaminants. The concentration of synthetic and volatile organic chemicals shall not exceed the MCLs specified in this section.
- (1) The following are MCLs for synthetic organic contaminants (SOCs).
Attached Graphic
- (2) The following are MCLs for volatile organic contaminants (VOCs).
Attached Graphic
- (3) Each public water system must certify annually to the executive director (using third party or manufacturer's certification) that when acrylamide or epichlorohydrin are used in drinking water systems, the combination (or product) of dose and monomer level does not exceed 0.05% dosed at 1.0 mg/L (or equivalent) for acrylamide and 0.01% dosed at 20 mg/L (or equivalent) for epichlorohydrin.
(c) Monitoring requirements for organic contaminants. Public water systems shall monitor for organic contaminants at the locations and frequency in paragraphs (1) and (2) of this subsection. All monitoring conducted under the requirements of this section must be conducted at sites designated in the public water system's monitoring plan. All samples must be taken during periods of normal operation when water representative of all sources used by the system is being used.
(1) SOC monitoring requirements. Monitoring of the SOC contaminants shall be conducted at the frequency and locations given in this paragraph.
(A) SOC monitoring locations. Monitoring of the SOC contaminants shall be conducted at the following locations.
- (i) Systems treating only groundwater shall sample for SOCs at every entry point to the distribution system which is representative of each well after treatment. Subsequent samples must be taken at the same entry point to the distribution system unless a change in conditions makes another entry point to the distribution system more representative of each source or treatment plant. The executive director must approve any change in sampling location.
- (ii) Systems using surface water and systems treating groundwater under the direct influence of surface water shall sample for SOCs at points in the distribution system that are representative of each source or at each entry point to the distribution system. Subsequent samples must be taken at the same entry points to the distribution system unless a change in conditions makes another entry point to the distribution system more representative of each source or treatment plant. The executive director must approve any change in sampling location.
(B) SOC monitoring frequency. Monitoring of the SOC contaminants shall be conducted at the following frequency.
- (i) Community and nontransient noncommunity water systems shall take four consecutive quarterly samples for each SOC contaminant listed in subsection (b)(1) of this section during each compliance period beginning with the initial compliance period.
- (ii) Community and nontransient noncommunity water systems serving more than 3,300 persons that do not detect a contaminant in the initial compliance period may reduce the sampling frequency to a minimum of two consecutive quarterly samples in one year during each repeat compliance period.
- (iii) Community and nontransient noncommunity water systems serving 3,300 persons or fewer that do not detect a contaminant in the initial compliance period may reduce the sampling frequency to a minimum of one sample during each repeat compliance period.
- (iv) Each public water system shall monitor at the time designated by the executive director within each compliance period.
(C) Increased SOC monitoring. The executive director may change the monitoring frequency for SOCs.
- (i) Systems which violate the SOC MCL's of subsection (b)(1) of this section as determined by subsection (f) of this section must monitor quarterly. After a minimum of four quarterly samples shows the system is in compliance and the executive director determines the system is reliably and consistently below the MCL, as determined by the methods specified in subsection (f) of this section, the executive director may allow the system to monitor annually. Systems which monitor annually must monitor during the quarter that previously yielded the highest analytical result.
(ii) The executive director may change the monitoring frequency if an organic SOC contaminant is detected in any sample.
- (I) If an organic SOC contaminant is detected in any sample, the system must monitor quarterly at each entry point to the distribution system at which a detection occurs.
- (II) After a groundwater system collects a minimum of two consecutive quarterly samples, the executive director may decrease the quarterly monitoring requirement specified in subclause (I) of this clause, if the system is reliably and consistently below the MCL.
- (III) After a surface water system or system treating groundwater under the direct influence of surface water collects a minimum of four consecutive quarterly samples, the executive director may decrease the quarterly monitoring requirement specified in subclause (I) of this clause, if the system is reliably and consistently below the MCL.
- (IV) After the executive director determines that a system is reliably and consistently below the MCL, the executive director may allow the system to monitor annually. Systems which monitor annually must monitor during the quarter that previously yielded the highest analytical result.
- (V) Systems which have three consecutive annual samples with no detection of a contaminant may be granted a waiver at the discretion of the executive director. The executive director will consider the waiver for each compliance period.
- (VI) If monitoring results in detection of one or more of certain related contaminants (i.e., heptachlor, and heptachlor epoxide), then subsequent monitoring shall analyze for all related contaminants.
- (iii) The executive director may increase the required SOC monitoring frequency, where necessary, to detect variations within the system (e.g., fluctuations in concentration due to seasonal use, changes in water source, etc.).
- (iv) The executive director may require a confirmation sample for positive or negative results. If a confirmation sample is required by the executive director, the result must be averaged with the first sampling result and the average used for the compliance determination as specified by subsection (f) of this section. The executive director has discretion to delete results of obvious sampling errors from this calculation.
(D) Waivers for SOC monitoring. The executive director may grant a waiver to reduce the SOC monitoring frequency from the monitoring frequency requirements of subsection (c)(1)(B) of this section, based on previous use of the contaminant within the watershed or zone of influence of the water source. Examples of use of a contaminant include transport, storage, or disposal. If a determination by the executive director reveals no previous use of the contaminant within the watershed or zone of influence, a waiver may be granted. If the executive director cannot determine whether the contaminant has been used in the watershed or if the contaminant has been used previously, then the following factors shall be used to determine whether a waiver is granted:
- (i) previous analytical results;
- (ii) the proximity of the system to a potential point or non-point source of contamination. Point sources include spills and leaks of chemicals at or near a water treatment facility or at drinking water sources, manufacturing, distribution, or storage facilities, or from hazardous and municipal waste landfills and other waste handling or treatment facilities. Non-point sources include the use of pesticides to control insects, weeds, or pests on agricultural areas, forest lands, home and garden property, or other land application uses;
- (iii) the environmental persistence and transport of the pesticide herbicide or contaminant;
- (iv) how well the water source is protected against contamination due to such factors as depth of the well, type of soil and the integrity of well construction. Surface water systems must consider watershed vulnerability and protection;
- (v) elevated nitrate levels at the water supply source; and
- (vi) use of PCBs in equipment used in the production, storage, or distribution of water (i.e., PCBs used in pumps, transformers, etc.).
(E) Compositing for SOC monitoring. The executive director may reduce the total number of samples required from a system for analysis by allowing the use of compositing. Composite samples from a maximum of five entry points to the distribution system are allowed. Compositing of samples must be done in the laboratory and analyzed within 14 days of sample collection.
- (i) If, in the composite sample, a detection of one or more SOC contaminants listed in subsection (b)(1) of this section occurs, then a follow-up sample must be taken from each entry point to the distribution system included in the composite and analyzed within 14 days of collection.
- (ii) If duplicates of the original SOC sample taken from each entry point to the distribution system used in the composite are available, the executive director may use these duplicates instead of resampling. The duplicate must be analyzed within 14 days of collection and the results reported to the executive director.
- (iii) Composting may only be permitted at entry points to the distribution system within a single system.
- (F) Initial SOC monitoring. If monitoring data are generally consistent with the requirements of this subsection (c)(1) of this section, then the executive director may allow systems to use that data to satisfy the monitoring requirement for the initial compliance period.
(2) VOC monitoring requirements. Monitoring of the VOC contaminants shall be conducted at the frequency and locations given in this paragraph.
(A) VOC monitoring locations. Monitoring of the VOC contaminants shall be conducted at the following locations.
- (i) Systems that use only groundwater shall sample for VOCs at every entry point to the distribution system which is representative of each well after treatment. Subsequent samples must be taken at the same entry point to the distribution system unless a change in conditions makes another entry point to the distribution system more representative of each source or treatment plant. The executive director must approve any change in sampling location.
- (ii) Surface water systems, systems using groundwater under the direct influence of surface water, and systems blending groundwater and surface water shall sample for VOCs at points in the distribution system that are representative of each source or at each entry point to the distribution system. Subsequent samples must be taken at the same entry points to the distribution system unless a change in conditions makes another entry point to the distribution system more representative of each source or treatment plant. The executive director must approve any change in sampling location.
(B) VOC monitoring frequency. Monitoring of the VOC contaminants shall be conducted at the following frequency.
- (i) Community and nontransient noncommunity water systems shall take four consecutive quarterly samples for each VOC contaminant listed in subsection (b)(2) of this section during each compliance period, beginning with the initial compliance period.
- (ii) If the initial monitoring for VOC contaminants has been completed by December 31, 1992, and the system did not detect any VOC contaminant listed in subsection (b)(2) of this section, the system shall take one sample annually beginning with the initial compliance period.
- (iii) After a minimum of three years of annual sampling, the executive director may allow groundwater systems with no previous detection of any VOC contaminant listed in subsection (b)(2) of this section to take one sample during each compliance period.
- (iv) Each community and nontransient groundwater system which does not detect a VOC contaminant listed in subsection (b)(2) of this section may be granted a waiver from the annual or triannual requirements of subsection (c)(2)(B)(ii) and (iii) of this section after completing the initial monitoring. For the purposes of this section, detection is defined as an analytical result of 0.0005 mg/L or greater. A waiver shall be effective for no more than six years (two compliance periods).
- (v) Each public water system shall monitor at the time designated by the executive director within each compliance period.
(C) Increased VOC monitoring. The executive director may change the monitoring frequency for VOCs.
- (i) Systems which violate the VOC MCLs of subsection (b)(2) of this section, as determined by subsection (f) of this section, must monitor quarterly. After a minimum of four consecutive quarterly samples that show the system is in compliance as specified in subsection (f) of this section and after the executive director determines that the system is reliably and consistently below the MCL, the executive director may allow the system to monitor annually during the quarter that previously yielded the highest analytical result.
- (ii) The executive director may require a confirmation sample for positive or negative results. If a confirmation sample is required by the executive director, the result must be averaged with the first sampling result and the average is used for the compliance determination as specified by subsection (f) of this section. The executive director has discretion to delete results of obvious sampling errors from this calculation.
(iii) If a VOC contaminant listed in subsection (b)(2) of this section is detected at a level exceeding 0.0005 mg/L in any sample, then:
- (I) the system must monitor quarterly at each entry point to the distribution system which resulted in a detection;
- (II) the executive director may decrease the quarterly monitoring requirement specified in subsection (c)(2)(C)(iii)(I) of this section provided it has determined that the system is reliably and consistently below the maximum contaminant level. In no case shall the executive director make this determination unless a groundwater system takes a minimum of two quarterly samples and a surface water system takes a minimum of four quarterly samples;
- (III) If the executive director determines that the system is reliably and consistently below the MCL, the executive director may allow the system to monitor annually. Systems which monitor annually must monitor during the quarter which previously yielded the highest analytical result;
- (IV) Systems which have three consecutive annual samples with no detection of a contaminant may be granted a waiver as specified in subsection (c)(2)(D) of this section; and
- (V) Groundwater systems which have detected one or more of the following two-carbon organic compounds: trichloroethylene, tetrachloroethylene, 1,2-dichloroethane, 1,1,1-trichloroethane, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene, or 1,1-dichloroethylene shall monitor quarterly for vinyl chloride. A vinyl chloride sample shall be taken at each entry point to the distribution system at which one or more of the two-carbon organic compounds was detected. If the result of the first analysis does not detect vinyl chloride, the executive director may reduce the quarterly monitoring frequency for vinyl chloride to one sample during each compliance period. Surface water systems are required to monitor for vinyl chloride as specified by the executive director.
- (iv) The executive director may increase the required VOC monitoring frequency, where necessary, to detect variations within the system (e.g., fluctuations in concentration due to seasonal use, changes in water source, etc.).
(D) Waivers for VOC monitoring. The executive director may grant a waiver after evaluating the previous use (including transport, storage, or disposal) of the contaminant within the watershed or zone of influence of the water sources. If a determination by the executive director reveals no previous use of the contaminant within the watershed or zone of influence, a waiver may be granted. If previous use of the contaminant is unknown or it has been used previously, then the following factors shall be used to determine whether a waiver is granted:
- (i) previous analytical results;
- (ii) the proximity of the system to a potential point or non-point source of contamination. Point sources include spills and leaks of chemicals at or near a water treatment facility or at drinking water sources manufacturing, distribution, or storage facilities, or from hazardous and municipal waste landfills and other waste handling or treatment facilities;
- (iii) the environmental persistence and transport of the contaminants;
- (iv) the number of persons served by the public water system and the proximity of a smaller system to a larger system;
- (v) how well the water source is protected against contamination (e.g., is it a surface or groundwater system). Groundwater systems must consider factors such as depth of the well, the type of soil, and well construction. Surface water systems must consider watershed protection;
- (vi) As a condition of the waiver a groundwater system must take one sample at each entry point to the distribution system during the time the waiver is effective (i.e., one sample during two compliance periods or six years) and update its vulnerability assessment considering the factors listed in this paragraph. Based on this updated vulnerability assessment the executive director must reconfirm that the system is not vulnerable. If the executive director does not make this reconfirmation within three years of the initial determination, then the waiver is invalid and the system is required to sample annually; and
- (vii) Community and nontransient surface water systems which do not detect a VOC contaminant listed in subsection (b)(2) of this section may be considered by the executive director for a waiver from the annual sampling requirements of subsection (c)(2)(B)(ii) of this section after completing the initial monitoring. Systems meeting this criteria must be determined by the executive director to be non-vulnerable based on a vulnerability assessment during each compliance period. Each system receiving a waiver shall sample at the frequency specified by the executive director (if any).
(E) Compositing for VOC monitoring. The executive director may reduce the total number of samples a system must analyze by allowing the use of compositing. Composite samples from a maximum of entry points to the distribution system are allowed. Compositing of samples must be done in the laboratory and analyzed within 14 days of sample collection.
- (i) If the VOC concentration in the composite sample is 0.0005 mg/L or greater for any contaminant listed in subsection (b)(2) of this section, then a follow-up sample must be taken and analyzed within 14 days from each entry point to the distribution system included in the composite.
- (ii) If duplicates of the original sample taken from each entry point to the distribution system used in the composite are available, the system may use these instead of resampling. The duplicate must be analyzed within 14 days of collection.
- (iii) Compositing may only be permitted by the executive director at entry points to the distribution system within a single system.
- (iv) Procedures for compositing VOC samples are as stated in 40 CFR §141.24 (f)(14)(iv).
- (d) Analytical requirements for organic contaminants. Analytical procedures shall be performed in accordance with §290.119 of this title (relating to Analytical Procedures). Testing for organic contaminants shall be performed at a laboratory certified by the executive director.
- (e) Reporting requirements for organic contaminants. Upon the request of the executive director, the owner or operator of a public water system must provide the executive director with a copy of the results of any test, measurement, or analysis required by this subsection. The copies must be submitted within ten days of the request or within ten days of their receipt by the public water system, whichever is later. The copies must be mailed to the Texas Natural Resource Conservation Commission, Water Supply Division, MC 155, P.O. Box 13087, Austin, Texas 78711-3087.
(f) Compliance determination for organic contaminants. Compliance with the MCLs of subsection (b)(1) and (2) of this section shall be determined based on the analytical results obtained at each entry point to the distribution system.
- (1) For systems which are sampling more than once a year, compliance is determined by a running annual average of all samples taken at each entry point to the distribution system. If the annual average at any entry point to the distribution system is greater than the MCL, the system commits an MCL violation. If the initial sample or a subsequent sample would cause the annual average to be exceeded, then the system is out of compliance immediately. Any samples below the detection limit shall be considered to be zero for purposes of calculating the annual average.
- (2) For systems which are sampling once a year or less, compliance is based on a single sample. If the level of a contaminant at any entry point to the distribution system is greater than the MCL, the system commits an MCL violation. If a confirmation sample is required the executive director, the determination of compliance will be based on the average of the two samples.
- (3) The executive director has the authority to determine compliance or initiate enforcement action based upon analytical results and other information compiled by their sanctioned representatives and agencies.
(g) Public notification requirements for organic contaminants. A public water system that violates the requirements of this section must notify the executive director and the system's customers. If a public water system has a distribution system separate from other parts of the distribution system with no interconnections, the executive director may allow the system to give public notice to only that portion of the system which is out of compliance.
- (1) A system that violates an MCL given in subsection (b) of this section, shall report to the executive director and notify the public as provided under §290.122(b) of this title.
- (2) A public water system which fails to conduct the monitoring required by this section must notify its customers of the violation in accordance with the requirements of §290.122(c) of this title (relating to Public Notification).
- (h) Best available technology (BAT) for organic contaminants. BAT for treatment of violations of MCLs in subsection (b) of this section are listed in 40 CFR §141.61. Copies are available for review in the Water Supply Division, Texas Natural Resource Conservation Commission, P.O. Box 13087, Austin, Texas 78711-3087.
Source Note:The provisions of this §290.107 adopted to be effective September 13, 2000, 25 TexReg 8880; amended to be effective May 16, 2002, 27 TexReg 4127.