Mo. Code Regs. Ann. tit. 10, § 10-5.510
PURPOSE: The purpose of this regulation is to reduce the emissions of nitrogen oxides in the St. Louis ozone nonattainment area. This regulation requires major sources of Nitrogen Oxides (NOX ) to install or comply with reasonably available control technology (RACT) as required under the Clean Air Act.
(1) Applicability.
(100) tons or greater per year of nitrogen oxides.
(B) Installations affected by this rule shall be in compliance no later than May 1, 2002. The director may grant an extension of the compliance deadline if the affected installation submits an alternative compliance plan no later than January 1, 2001. The alternative compliance plan shall include the following items:
analysis of the air quality benefit that will occur if the compliance date is extended;
explanation of the reasons why the owner or operator believes that compliance with the applicable NOx emissions limit by May 1, 2002 is impractical;
affected unit;
which the owner or operator will complete the following milestones for each affected unit:
mits;
of new units or control equipment;
new units or control equipment; and
NOx emissions limitation established in this rule; and
requests.
(C) Exemptions. The requirements of this rule shall not apply to the following emission units:
input of less than fifty (50) million British thermal units (mmBtu) per hour;
engine having a rated energy output capacity of less than five hundred (500) horsepower or a maximum heat input capacity of twenty (20) mmBtu per hour or less;
having a rated maximum heat input capacity of less than twenty (20) mmBtu per hour;
tionary internal combustion engine, stationary combustion turbine, start up unit, or black start unit which operates less than seven hundred and fifty (750) hours annually and less than four hundred (400) hours during ozone season;
sions unit;
to meet a more stringent state or federal NOx emissions limitation;
required to comply with this rule with actual annual NOx emissions of thirty (30) tons per year or less. This exemption shall cease to apply to a unit if the unit ever exceeds thirty (30) tons per year of actual NOx emissions for any calendar year. Any unit that becomes affected by this rule due to failure to maintain this exemption after January 1, 2000 shall immediately notify the department in writing that the rule applies. The unit shall be in compliance with the applicable provisions of this rule within twenty-four (24) months after notifying the department or May 1, 2002, whichever is later;
ance with Phase II acid rain requirements; and
rated heat input capacity of less than fifty (50) mmBtu per hour.
(2) Definitions.
corner of the furnace where the vertical furnace walls meet. Both pulverized coal and air are directed from the furnace corners along a line tangential to a circle lying in a horizontal plane of the furnace.
(3) General Provisions.
(A) No owner or operator of a boiler with a maximum rated heat input capacity of one hundred (100) mmBtu per hour or greater shall allow the unit to emit NOx in excess of the emission rates specified in Table 1 as measured pursuant to section (5) of this rule.
Table 1
Maximum Allowable NOX Emission Rates for Boilers (Pounds of NOX per mmBtu) (cid:41)(cid:88)(cid:72)(cid:79)(cid:18)(cid:37)(cid:82)(cid:76)(cid:79)(cid:72)(cid:85)(cid:3)(cid:55)(cid:92)(cid:83)(cid:72)(cid:3) (cid:41)(cid:76)(cid:85)(cid:76)(cid:81)(cid:74)(cid:3)(cid:38)(cid:82)(cid:81)(cid:73)(cid:76)(cid:74)(cid:88)(cid:85)(cid:68)(cid:87)(cid:76)(cid:82)(cid:81)(cid:86)(cid:3) (cid:3) (cid:55)(cid:68)(cid:81)(cid:74)(cid:72)(cid:81)(cid:87)(cid:76)(cid:68)(cid:79)(cid:3) (cid:58)(cid:68)(cid:79)(cid:79)(cid:3) (cid:38)(cid:92)(cid:70)(cid:79)(cid:82)(cid:81) (cid:54)(cid:87)(cid:82)(cid:78)(cid:72)(cid:85)(cid:3) (cid:72)(cid:3) (cid:42)(cid:68)(cid:86)(cid:72)(cid:82)(cid:88)(cid:86)(cid:3)(cid:41)(cid:88)(cid:72)(cid:79)(cid:86)(cid:3) (cid:19)(cid:17)(cid:21)(cid:3) (cid:19)(cid:17)(cid:21)(cid:3) (cid:19)(cid:17)(cid:24)(cid:3) (cid:16)(cid:3) (cid:50)(cid:81)(cid:79)(cid:92)(cid:3) (cid:39)(cid:76)(cid:86)(cid:87)(cid:76)(cid:79)(cid:79)(cid:68)(cid:87)(cid:72)(cid:3)(cid:50)(cid:76)(cid:79)(cid:3) (cid:19)(cid:17)(cid:22)(cid:3) (cid:19)(cid:17)(cid:22)(cid:3) (cid:16)(cid:3) (cid:16)(cid:3) (cid:53)(cid:72)(cid:86)(cid:76)(cid:71)(cid:88)(cid:68)(cid:79)(cid:3)(cid:50)(cid:76)(cid:79)(cid:3) (cid:19)(cid:17)(cid:22)(cid:3) (cid:19)(cid:17)(cid:22)(cid:3) (cid:16)(cid:3) (cid:16)(cid:3) (cid:38)(cid:82)(cid:68)(cid:79)(cid:3)(cid:177)(cid:3)(cid:58)(cid:72)(cid:87)(cid:3) (cid:3)(cid:16)(cid:3) (cid:16)(cid:3) (cid:19)(cid:17)(cid:27)(cid:25)(cid:3) (cid:16)(cid:3) (cid:37)(cid:82)(cid:87)(cid:87)(cid:82)(cid:80)(cid:3) (cid:38)(cid:82)(cid:68)(cid:79)(cid:3)(cid:177)(cid:3)(cid:39)(cid:85)(cid:92)(cid:3) (cid:19)(cid:17)(cid:23)(cid:24)(cid:3) (cid:19)(cid:17)(cid:24)(cid:3) (cid:16)(cid:3) (cid:19)(cid:17)(cid:24)(cid:3) (cid:37)(cid:82)(cid:87)(cid:87)(cid:82)(cid:80)(cid:3)
(100) mmBtu per hour shall complete an annual adjustment or tune up on the combustion process. This adjustment or tune up shall include at a minimum the following items:
replacement of fuel burning equipment, including the burners and moving parts necessary for proper operation as specified by the manufacturer;
characteristics and adjustments necessary to minimize total emissions of NOX and, to the extent practicable, minimize emissions of carbon monoxide; and
trol system and adjustments necessary to ensure proper calibration and operation as specified by the manufacturer.
(C) No owner or operator of a stationary combustion turbine shall allow or permit the discharge of any NOx emissions in excess of the following limits:
(ppm), corrected to fifteen percent (15%) oxygen, for combustion turbines firing gaseous fuel only; and
ed to fifteen percent (15%) oxygen, for combustion turbines firing distillate oil or diesel fuel.
(20) mmBtu per hour shall allow or permit the discharge of NOX emissions in excess of the following limits:
only gaseous fuels—
horsepower-hour for engines which are rated equal to or greater than five hundred (500) horsepower and less than one thousand (1,000) horsepower; or
horsepower-hour for engines which are rated equal to or greater than one thousand (1,000) horsepower;
only gaseous fuels—
hour for engines which are rated equal to or greater than five hundred (500) horsepower and less than one thousand (1,000) horsepower; or
hour for engines which are rated equal to or greater than one thousand (1,000) horsepower;
fuel or distillate oil—
horsepower-hour for engines which are rated equal to or greater than five hundred (500) horsepower and less than one thousand eight hundred (1,800) horsepower; or
horsepower-hour for engines which are rated equal to or greater than one thousand eight hundred (1,800) horsepower; or
4. For engines which burn dual fuels—
hour for engines which are rated equal to or greater than five hundred (500) horsepower and less than two thousand (2,000) horsepower; or
horsepower-hour for engines which are rated equal to or greater than two thousand (2,000) horsepower.
unless good combustion practices are implemented. Each portland cement kiln shall develop a good combustion practice plan that identifies appropriate kiln operating parameters necessary to ensure minimum NOx formation. Each kiln operator shall be trained to operate the kiln in accordance with the plan. The parameters included in the plan shall include at a minimum the following:
surrogate parameter;
operating range or a surrogate parameter; and
dures for each parameter.
(G) Emissions Averaging. An owner or operator may comply with the requirements of subsections (3)(A), (3)(C), (3)(D), (3)(E) and (3)(H) of this rule by averaging between two (2) or more similar emission units provided they are located in the St. Louis ozone nonattainment area and provided that both units are required to comply with the subsections (3)(A), (3)(C), (3)(D), (3)(E) or (3)(H) of this rule.
weighted average of actual NOx emissions from the units on a monthly basis. The averaged emissions rate for the units must be equal to or less than the allowable emissions rate for the units as defined in this rule. An owner or operator who elects to comply with an average NOx emission limit shall use the following equation to determine compliance:
∑(actual NOx emission rate from each unit * actual monthly heat input from each unit) ≤ ∑(allowable NOx emission rate from each unit * actual monthly heat input from each unit)
ed from actual data from continuous emissions monitoring system (CEMS), PEMS or established through stack testing at several loads.
occur between emission units operated under same owner unless a binding legal agreement between two (2) owners is filed with the director and provided the emission units are located in the St. Louis ozone nonattainment area. The binding legal agreement must specify the following:
(2) owners or operators to comply with the averaging provisions;
which will be used for averaging;
units will comply with the averaging provisions;
monthly data used to determine compliance with the averaging provisions; and
ator who will be responsible for the monthly compliance reports.
(H) Case-By-Case RACT Studies.
sions unit subject to this rule but not specifically identified in subsection (3)(A), (3)(B), (3)(C), (3)(D), (3)(E) or (3)(F) of this rule shall conduct and submit by July 1, 2000 a detailed engineering and RACT study for those emission units subject to this rule.
imum, include the following information:
the RACT requirements;
ed emission unit and the types of fuel combusted or the types and quantities of materials processed or produced by each emission unit;
emission unit and its operating characteristics;
actual NOx emissions from each affected emission unit and associated supporting documentation;
requirements of subsection (3)(H) of this rule, including technical and economic support documentation identified in subsection (3)(G) of this rule for each affected emission unit;
mentation of the RACT proposal as expeditiously as practicable but not later than April 1, 2001, including interim dates for the issuance of purchase orders, start and completion of process technology and control technology changes and the completion of compliance testing;
ing and reporting procedures proposed to demonstrate compliance with RACT;
permit amendment or application to incorporate the provisions of the RACT proposal; and
by the department that is necessary for the evaluation of the RACT proposal.
include:
options for the affected emission unit in descending order of control effectiveness. Available control options are air pollution control technologies or techniques with a reasonable potential for application to the emission unit. Air pollution control technologies and techniques include the application of production process or methods and control systems for NOx. The control technologies and techniques shall include existing controls for the source category and technology transfer controls applied to similar source categories;
sibility of the available control options as required by paragraph (3)(G)1. of this rule. The evaluation of technical feasibility shall be based on physical, chemical and engineering principles. If an analysis is determined to be technically infeasible, the technical difficulties which would preclude the successful use of the control options on the affected emission unit shall be identified;
ble control options in order of overall control effectiveness for NOx emissions. The list shall present the array of control options and shall include, at a minimum, the following information:
before implementation of each control option;
tion potential or the estimated control efficiency of each control option;
the application of each control option; and
control option, including both overall cost effectiveness and incremental cost effectiveness; and
of each control option consistent with OAQPS Control Cost Manual (Fourth Edition), EPA 450/3-90-006 January 1990 and subsequent revisions. The evaluation shall be conducted in accordance with the following requirements:
evaluated in terms of dollars per ton of NOx emission reduction;
calculated on average and incremental bases for each option. Average cost effectiveness is calculated as the annualized cost of the control option divided by the baseline emissions rate minus the control option emission rate, as shown by the following formula:
Cost Effectiveness Equation
Average Cost Effectiveness ($/ton NOx removed) =
Total annualized cost of the control option ($/yr) Baseline emission rate (tons/yr) – Control option emission rate (tons/yr)
graph, baseline emission rate represents the maximum emissions before the implementation of the control option. The baseline emissions rate shall be established using either test results or approved emission factors and historical operating data; and
graph, the incremental cost effectiveness calculation compares the costs and emission level of a control option to those of the next most stringent option, as shown by the following formula: Incremental Cost Equation Incremental Cost per incremental ton removed ($/ton)=
Total annualized cost for a control option ($/yr) – Total annualized cost for the next most stringent control option ($/yr) The emission rate for the more stringent control option (tons/yr) – The emission rate for the control option (tons/yr)
shall provide a case-specific RACT determination which shall be implemented by the owner or operator of the unit as expeditiously as practicable but in no case later than May 1, 2002. This case-specific RACT determination shall be submitted to the administrator of the U.S. Environmental Protection Agency.
(4) Reporting and Record Keeping.
(A) Reporting. Reporting shall be based on the test methods identified in section (5) of this rule.
sions unit subject to subsections (3)(A), (3)(C), (3)(D), (3)(E), (3)(F) and (3)(G) of this rule shall comply with the following requirements:
unit that uses a CEMS to demonstrate compliance, an annual report containing the date, time and emissions rate in pounds NOx per mmBtu of all thirty (30)-day rolling averages greater than the emission rates allowed under section (3) of this rule;
unit which uses stack tests to demonstrate compliance, an annual report identifying monthly fuel usage and monthly total heat input; and
stack tests completed after controls are effective to the director within sixty (60) days Specific to the St. Louis Metropolitan Area
after completion of sample and data collection.
unit subject to subsection (3)(H) of this rule shall comply with the reporting requirements established in the case-by-case RACT determination approved by the director. The owners or operators of emissions units complying with the averaging provisions of subsection (3)(H) shall submit to the director within thirty (30) days after the end of each calendar month a compliance report stating the averaged emission rate. The compliance report shall also include the data used to determine the averaged emission rate. If the average emission rate exceeds the allowable emission rate, the owners and operators shall determine which owner or operator is responsible for the violation. The owners and operators in the compliance report shall submit the identity of the responsible owner or operator. The department will take enforcement action against only the owner or operator responsible for the violation. However, if the owners or operators do not submit within thirty (30) days the identity of the violator, both owners or operators shall be responsible for the violation.
(B) Record Keeping.
sions unit subject to subsections (3)(A), (3)(C), (3)(D), (3)(E), (3)(F) and (3)(G) of this rule shall maintain records of the following:
basis unless the unit is operating a CEMS or predictive emissions monitoring system (PEMS);
sions unit on a monthly basis unless the unit is operating a CEMS or a PEMS;
ducted to meet the requirements of this rule;
CEMS or a PEMS necessary to convert the monitoring data to the units of the applicable emission limitation;
mance evaluations conducted in the past year;
calibration checks;
device and performance testing measurements;
tenance performed on monitoring systems and devices; and
ing which the CEMS was inoperative, except for zero and span checks, and the nature of the repairs and adjustments performed to make the system operative.
sions unit subject to subsection (3)(H) of this rule shall comply with the record keeping requirements established in the case-by-case RACT determination approved by the director.
period of five (5) years and made available to the department upon request.
(5) Test Methods.
(A) Compliance Testing. Initial compliance for all units subject to subsections (3)(A), (3)(C), (3)(D), (3)(E) or (3)(G) of this rule shall be determined through a stack test performed prior to the implementation date under section (1) of this rule except those units complying with the provisions of subsection (5)(B) of this rule. After the initial stack test, stack tests shall be required every three (3) years to determine compliance except for units complying with the provisions of subsection (5)(B) of this rule. The following test methods shall be used for all stack tests:
Method 7, 7A, 7C, 7D or 7E shall be used to determine NOx concentrations in stack gases;
1A, 2, 2A, 2B, 2C, 2D, 2F, 2G, or 2H shall be used to determine the exit velocity of stack gases;
3 or 3A shall be used to determine carbon dioxide, oxygen, excess air and molecular weight of stack gases;
4 shall be used to determine moisture content of stack gases from applicable stationary sources;
19 shall be used to determine (calculate or compute) NOx (heat input specific) emission rates (pound per mmBtu); and
40 CFR Part 60 Appendix A, Method 20 may be used to determine NOx concentrations.
(B) Monitoring. As an alternative to the compliance testing required under subsection (5)(A) for units subject to subsections (3)(A), (3)(C), (3)(D), (3)(E) and (3)(G) of this rule, an owner or operator of an emission unit may install, calibrate, maintain and operate a CEMS or a PEMS approved by the director and the U.S. Environmental Protection Agency (EPA), or use an equivalent procedure for measuring or estimating NOx emissions approved by the director and the EPA. For units operating CEMS, PEMS or an equivalent procedure for estimating NOxemissions, the following requirements shall apply: 10 CSR 10-5
thirty (30)-day rolling average;
lating NOx emissions rates;
60.13(d), (e) and (f) and 40 CFR Part 60 Appendix B, Performance Specification 2 shall be followed, or other procedures approved by the director; for the installation, evaluation and operation of CEMS or PEMS;
tion drift tests shall be performed in accordance with 40 CFR Part 60 Appendix F, or other tests approved by the director; and
ed in accordance with 40 CFR Part 75 are deemed to be approved by the director to meet the monitoring and quality assurance requirements of this subsection.
AUTHORITY: section 643.050, RSMo 2000.* Original rule filed July 15, 1999, effective Feb. 29, 2000. Amended: Filed Aug. 26, 2005, effective May 30, 2006. *Original authority: 643.050, RSMo 1965, amended 1972, 1992, 1993, 1995.