Mo. Code Regs. Ann. tit. 10, § 10-5.330
PURPOSE: This rule restricts the emissions of volatile organic compounds from industrial surface coating operations.
(1) Applicability.
(D) Exemptions. This rule is not applicable to the following:
vehicles, if production is less than thirty-five (35) vehicles per day;
rial, building, and installation maintenance operations;
mance testing, and quality control of coatings and surface coated products;
coatings to buildings, building components, and stationary structures;
aerospace vehicles or components at an aerospace manufacture or rework installation that—
and/or aerospace-specific exemptions of 10 CSR 10-5.295; or
because the installation’s potential to emit volatile organic compounds from aerospace surface coating and cleaning is twenty-five (25) tons per year or less;
furniture or wood furniture components at a wood furniture manufacturing installation that—
and/or wood furniture-specific exemptions of 10 CSR 10-5.530; or
because the installation’s potential to emit volatile organic compounds from wood furniture coating and cleaning is less than twentyfive (25) tons per year;
tions that are subject to a Reasonably Available Control Technology determination under 10 CSR 10-5.520;
coatings that are subject to the requirements of 10 CSR 10-5.450;
to the requirements of 10 CSR 10-5.340 or 10 CSR 10-5.442;
cles used for internal company operations, including, but not limited to, work stands; scaffolding; jigs; tooling; dollies; tow bars; aircraft ground support equipment; portable equipment used for maintenance, testing, fabrication, or repair; toolboxes; storage bins; shelving; and other manufacturing or warehouse support items;
not have a VOC limit in section (3) of this rule;
less than 0.17 pounds of VOC per gallon of coating (less water and exempt compounds) as applied;
primers, and sealant primers that are supplied by the manufacturer or supplier in containers with a net volume of sixteen (16) fluid ounces or less, or a net weight of one (1) pound or less, except plastic cement welding adhesives and contact adhesives;
by the manufacturer or supplier in containers with a net volume of one (1) gallon or less; and
primers, sealant primers, surface preparation, and cleanup solvents that are used in the following operations:
the adhesive is labeled for tire repair only;
of aerospace or undersea-based weapon systems;
the manufacture of medical devices or in the manufacture of medical equipment; and
which adhesives are used to bond clear, polyester acetate laminate to wood with lamination equipment installed prior to July 1, 1992.
(3) General Provisions. General provisions for specific coatings may be found in the following subsections of section (3) of this rule:
(10/31/14)* JOHN R. ASHCROFT Specific to the St. Louis Metropolitan Area
Industrial Adhesive Application (3)(K)
(A) Large Appliance Coatings.
apply to the surface coating of doors, cases, lids, panels, and interior support parts of the following residential and commercial products:
2. Emission limits.
or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
owner or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
JOHN R. ASHCROFT (10/31/14)*
ance. The emission limits in paragraph (3)(A)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds) per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limits in paragraph (3)(A)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
March 1, 2012, one (1) or a combination of the following equipment shall be used for coating application, unless achieving compliance by using an add-on control system per subparagraph (3)(A)3.C. of this rule:
spray equipment;
position;
capable of achieving a transfer efficiency 10 CSR 10-5
containers;
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
coatings, thinners, and cleaning materials;
cleaning materials in closed containers or pipes from one (1) location to another; and
cleaning of application, storage, mixing, and conveying equipment by ensuring that equipment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
of this rule do not apply to the following types of coatings and coating operations:
conducting coatings.
(B) Metal Furniture Coatings.
apply to surface coating of any furniture made of metal or any metal part that will be assembled with other metal, wood, fabric, plastic, or glass parts to form a furniture piece.
2. Emission limits.
or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of three (3.0) pounds of VOC per gallon of coating (minus water and exempt compounds) as delivered to the coating applicator(s).
owner or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
| Coating | Subsection | equivalent or better than achieved by HVLP |
|---|---|---|
| Large Appliance Coatings | (3)(A) | spraying. |
| Metal Furniture Coatings | (3)(B) | 5. Work practices. On or after March 1, |
| Automobile and Light-Duty Truck Assembly Coatings | (3)(C) | 2012, work practices shall be used to mini- |
| Paper, Film, and Foil Coatings | (3)(D) | mize VOC emissions from solvent storage, |
| mixing operations, and handling operations | ||
| Magnet Wire Coatings | (3)(E) | |
| for coatings, thinners, cleaning materials, and | ||
| Coil Coatings | (3)(F) | |
| waste materials. Work practices shall include, | ||
| Can Coatings | (3)(G) | |
| but not be limited to, the following: | ||
| Vinyl and Fabric Coatings | (3)(H) | |
| A. Store all VOC-containing coatings, | ||
| Flat Wood Paneling Coatings | (3)(I) | |
| thinners, and cleaning materials in closed | ||
| Miscellaneous Metal and Plastic Parts Coatings | (3)(J) |
ance. The emission limits in paragraph (3)(B)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds) per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limits in paragraph (3)(B)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
March 1, 2012, one (1) or a combination of the following equipment shall be used for coating application, unless achieving compliance by using an add-on control system per subparagraph (3)(B)3.C. of this rule:
position;
capable of achieving a transfer efficiency equivalent or better than achieved by HVLP spraying.
2012, work practices shall be used to mini-
coatings, thinners, and cleaning materials;
cleaning materials in closed containers or pipes from one (1) location to another; and owner or operator of an automobile or light-
cleaning of application, storage, mixing, and allow, or permit the discharge into the ambiconveying equipment by ensuring that equipent air of any VOC in excess of the following: ment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
of this rule do not apply to the following types of coatings and coating operations:
conducting coatings.
(C) Automobile and Light-Duty Truck Assembly Coatings.
apply to automobile and light-duty truck surface coating operations performed in an automobile or light-duty truck assembly installation.
2. Emission limits.
or operator of an automobile or light-duty truck assembly installation may cause, allow, or permit the discharge into the ambient air of any VOC in excess of the following: Automobile and Light-Duty Truck Assembly Coatings Coating Category Emission Limit 15.1 pounds of VOC per gallon of
3.0 pounds of VOC per gallon of
All Other Coatings coating (minus water and exempt compounds)
B. On or after March 1, 2012, no
Automobile and Light-Duty Truck Assembly Coatings
Coating Category Emission Limit RT(cid:3)(cid:31)(cid:3)(cid:19)(cid:17)(cid:19)(cid:23)(cid:19) (cid:19)(cid:17)(cid:19)(cid:23)(cid:19)(cid:3)(cid:100)(cid:3)RT(cid:3)(cid:31)(cid:3)(cid:19)(cid:17)(cid:20)(cid:25)(cid:19) RT(cid:3)(cid:116)(cid:3)(cid:19)(cid:17)(cid:20)(cid:25)(cid:19) 0.7 pounds of (cid:19)(cid:17)(cid:26)(cid:3)(cid:238)(cid:3)(cid:22)(cid:24)(cid:19)(cid:3)(cid:19)(cid:17)(cid:20)(cid:25)(cid:19)(cid:16)RT(cid:3) Electrodeposition No VOC VOC per pounds of VOC per primer (EDP) Emission gallon of gallon of coating solids Limit coating solids deposited deposited Primer-surfacer 12.0 pounds of VOC per gallon of coating solids deposited Topcoat 12.0 pounds of VOC per gallon of coating solids deposited Combined Primer- 12.0 pounds of VOC per gallon of coating solids deposited Surfacer and Topcoat 4.8 pounds of VOC per gallon of coating (minus water and Final repair exempt compounds)
(10/31/14)* JOHN R. ASHCROFT
| mize VOC emissions from solvent storage, | Topcoat | |
|---|---|---|
| coating solids deposited | ||
| mixing operations, and handling operations | ||
| Spray Primer or | 15.1 pounds of VOC per gallon of | |
| for coatings, thinners, cleaning materials, and | ||
| Primer Surfacer | coating solids deposited | |
| waste materials. Work practices shall include, | ||
| but not be limited to, the following: | Electrodeposition | 1.4 pounds of VOC per gallon of |
| A. Store all VOC-containing coatings, | Primer | coating solids deposited |
| thinners, and cleaning materials in closed | 4.8 pounds of VOC per gallon of | |
| containers; | Final Repair | coating (minus water and exempt |
| B. Ensure that mixing and storage | compounds) | |
| containers used for VOC-containing coatings, | Miscellaneous Metal | |
| 3.5 pounds of VOC per gallon of | ||
| thinners, coating related waste, and cleaning | Parts, Extreme | |
| coating (minus water and exempt | ||
| materials are kept closed at all times except | Performance, and Air | |
| compounds) | ||
| when depositing or removing these materials; | Dried Coatings |
Specific to the St. Louis Metropolitan Area
Automobile and light-duty truck
Automobile and light-duty truck 5.8 lubricating wax/compound
ance. The emission limits in paragraph (3)(C)2. of this rule shall be achieved through the following:
topcoat; and combined primer-surfacer and topcoat. The VOC emission rate, expressed as pounds of VOC per gallon of coating solids deposited, is determined by the procedures in the U.S. Environmental Protection Agency (EPA) document Protocol for Determining the Daily Volatile Organic Compound Emission Rate of Automobile and Light-Duty Truck Primer-Surfacer and Topcoat Operations (EPA-453/R-08-002), dated September 2008. The surface coating unit is in compliance if the emission rate is less than or equal to the emission limit in paragraph (3)(C)2. of this rule;
Determine the monthly volume-weighted average VOC emission rate of the EDP coating unit, expressed as pounds of VOC per gallon of coating solids deposited, per subparagraph (5)(C)3.D. of this rule. The EDP coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(C)2. of this rule;
the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon
JOHN R. ASHCROFT (10/31/14)*
ance if this value is less than or equal to the
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
taining coatings, thinners, and cleaning materials;
and cleaning materials in closed containers or pipes from one (1) location to another; and
from the cleaning of application, storage, mixing, and conveying equipment by ensuring that equipment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
subject to subparagraph (3)(C)4.A. of this rule shall develop and implement a work practice plan to minimize VOC emissions from cleaning and purging of equipment associated with all coating operations for which emission limits are specified in paragraph (3)(C)2. of this rule. The plan shall specify practices and procedures to ensure that VOC emissions from the following operations are minimized:
grates;
prior to controls;
pounds of VOC per gallon of coating (minus water and exempt compounds) as delivered to the coating applicator(s).
owner or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
ance. The emission limits in paragraph (3)(D)2. of this rule shall be achieved through one (1) of the following:
A. VOC content of coatings.
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds) per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(D)2. of this rule.
| 5.4 emission limit in paragraph (3)(C)2. of this | B. Coating performed on or in-line | ||||
|---|---|---|---|---|---|
| sealer | |||||
| rule. | with any offset lithographic, screen, letter- | ||||
| Automobile and light-duty truck | |||||
| 5.4 | 4. Work practices and work practice press, flexographic, rotogravure, or digital | ||||
| deadener | |||||
| plan. | printing press that is part of a printing pro- | ||||
| Automobile and light-duty truck | cess; and | ||||
| 1.7 | A. Work practices. On or after | ||||
| gasket/gasket-sealing material | C. | Size | presses | and | on-machine |
| March 1, 2012, work practices shall be used | |||||
| Automobile and light-duty truck | coaters on papermaking machines that apply | ||||
| 5.4 to minimize VOC emissions from storage, | |||||
| underbody coating | sizing or water-based clays. | ||||
| mixing operations, and handling operations | |||||
| Automobile and light-duty truck for coatings, thinners, cleaning materials, and | 2. Emission limits. | ||||
| 5.4 | |||||
| trunk interior coating waste materials. Work practices shall include, | A. Prior to March 1, 2012, no owner | ||||
| Automobile and light-duty truck but not be limited to, the following: | or operator of a surface coating unit subject | ||||
| 1.7 | to this subsection may cause, allow, or permit | ||||
| bedliner | (I) Store all VOC-containing coat- | ||||
| Automobile and light-duty truck ings, thinners, and cleaning materials in | the discharge into the ambient air of any | ||||
| 6.3 | VOCs in excess of two and nine-tenths (2.9) | ||||
| weatherstrip adhesive closed containers; |
| Miscellaneous Materials | of coating (minus water and exempt com- | ment; |
|---|---|---|
| pounds) per subparagraph (5)(C)3.A. of this | (VII) Cleaning external spray booth | |
| Emission Limit | ||
| rule. The surface coating unit is in compli- | areas; and | |
| pounds of VOC per | ||
| ance if this value is less than or equal to the | (VIII) Other housekeeping mea- | |
| gallon of coating | sures, such as keeping solvent-laden rags in | |
| emission limits in paragraph (3)(C)2. of this | ||
| (minus water and | closed containers. | |
| rule; and | ||
| Material exempt compounds) | (D) Paper, Film, and Foil Coatings. | |
| D. All other coatings. Determine the | ||
| Automobile and light-duty truck | monthly volume-weighted average VOC con- | 1. The requirements in this subsection |
| 7.5 | ||
| glass bonding primer | tent of all coatings used in a surface coating | apply to paper, film, and foil coating opera- |
| Automobile and light-duty truck | unit, expressed as pounds of VOC per gallon | tions, with the exception of the following: |
| 2.1 | ||
| adhesive | of coating (minus water and exempt com- | A. Paper, film, and foil surface coat- |
| Automobile and light-duty truck | pounds) per subparagraph (5)(C)3.E. of this | ing units with potential to emit below twenty- |
| 5.4 | five (25) tons per year of VOC from coating, | |
| cavity wax | rule. The surface coating unit is in compli- |
Determine the daily mass-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per pound of coating solids per subparagraph (5)(C)3.C. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limits in paragraph (3)(D)2. of this rule; or
tem is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
2012, work practices shall be used to minimize VOC emissions from solvent storage, mixing operations, and handling operations for coatings, thinners, cleaning materials, and waste materials. Work practices shall include, but not be limited to, the following:
thinners, and cleaning materials in closed containers;
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
coatings, thinners, and cleaning materials;
cleaning materials in closed containers or pipes from one (1) location to another; and
cleaning of application, storage, mixing, and conveying equipment by ensuring that equipment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
(E) Magnet Wire Coatings.
apply to the coating of electrically insulating varnish or enamel to aluminum or copper wire for use in electrical machinery.
tor of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of one and seven-tenths (1.7) pounds of VOC per gallon of coating (minus water and exempt compounds) as delivered to the coating applicator(s).
ance. The emission limits in paragraph (3)(E)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(E)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
(F) Coil Coatings.
apply to the surface coating of any flat metal sheet or strip that comes in rolls or coils.
tor of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of two and six-tenths (2.6) pounds of VOC per gallon of coating (minus water and exempt compounds) as delivered to the coating applicator(s).
ance. The emission limits in paragraph (3)(F)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(F)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
(G) Can Coatings.
apply to the surface coating of cans.
tor of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any volatile organic compounds, as delivered to the coating applicator(s), in excess of the following:
ance. The emission limits in paragraph (3)(G)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(G)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
(H) Vinyl and Fabric Coatings.
apply to vinyl coating and fabric coating.
tor of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any volatile organic compounds, as delivered to the coating applicator(s), in excess of the following:
ance. The emission limits in paragraph
(10/31/14)* JOHN R. ASHCROFT Specific to the St. Louis Metropolitan Area
(3)(H)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(H)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
(I) Flat Wood Paneling Coatings.
2012, no owner or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of two and onetenths (2.1) pounds of VOC per gallon of coating (minus water and exempt compounds) as delivered to the coating applicator(s).
ance. The emission limits in paragraph (3)(I)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(I)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall
JOHN R. ASHCROFT (10/31/14)*
control system efficiency is greater than or equal to the required control system efficiency; or
tem is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
2012, work practices shall be used to minimize VOC emissions from solvent storage, mixing operations, and handling operations for coatings, thinners, cleaning materials, and waste materials. Work practices shall include, but not be limited to, the following:
thinners, and cleaning materials in closed containers;
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
coatings, thinners, and cleaning materials;
apply to the surface coating of all other miscellaneous metal and plastic parts including, but not limited to, the following:
and machinery;
machinery and equipment;
coats metal parts or products under the Standard Industrial Classification Code of major groups #33, #34, #35, #36, #37, #38, and #39;
equipment;
parts;
components;
ment;
nents when the coating is applied in a surface coating unit as defined in 10 CSR 10-6.020.
2. Emission limits.
or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
Emission Limit
pounds of VOC per gallon of coating (minus water
Mail Boxes and Shutters 3.5
owner or operator of a surface coating unit subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s):
| apply to the coating of the following: | cleaning materials in closed containers or | Coating Category | and exempt compounds) |
|---|---|---|---|
| A. Printed interior panels made of | pipes from one (1) location to another; and | MetalParts | |
| hardwood plywood and thin particleboard; | F. Minimize VOC emissions from the | ClearCoat | 4.3 |
| B. Natural finish hardwood plywood | cleaning of application, storage, mixing, and | ExtremePerformanceCoatings | 3.5 |
| panels; | conveying equipment by ensuring that equip- | AirDriedCoatings | 3.5 |
| C. Hardboard paneling with Class II | ment cleaning is performed without atomiz- | AllOtherCoatings | 3.0 |
| finishes; | ing the cleaning solvent and all spent solvent | PlasticParts | 3.5 |
| D. Exterior siding; and | is captured in closed containers. | RailroadCars | 3.5 |
| E. Tileboard. | (J) Miscellaneous Metal and Plastic Parts | ||
| Farm Implements and Machinery | 3.5 | ||
| 2. Emission limits. On or after March 1, | Coatings. | ||
| Heavy-Duty Trucks | 3.5 |
ance. The emission limits in paragraph (3)(J)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), per subparagraph (5)(C)3.A. of this rule. The surface coating unit is in compliance if this value is less than or equal to the emission limit in paragraph (3)(J)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The surface coating unit is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be ninety percent (90%) or greater.
28 CODE OF STATE REGULATIONS (10/31/14)* JOHN R. ASHCROFT Specific to the St. Louis Metropolitan Area
March 1, 2012, one (1) or a combination of the following equipment shall be used for coating application, unless achieving compliance by using an add-on control device per subparagraph (3)(J)3.C. of this rule:
position;
capable of achieving a transfer efficiency equivalent or better than achieved by HVLP spraying.
2012, work practices shall be used to minimize VOC emissions from solvent storage, mixing operations, and handling operations for coatings, thinners, cleaning materials, and waste materials. Work practices shall include, but not be limited to, the following:
thinners, and cleaning materials in closed containers;
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
coatings, thinners, and cleaning materials;
cleaning materials in closed containers or pipes from one (1) location to another; and
cleaning of application, storage, mixing, and conveying equipment by ensuring that equipment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
limits in paragraph (3)(J)2. of this rule do not apply to the following types of coatings and coating operations:
conducting coatings;
ings; and
form a coating.
tion equipment requirements in paragraph (3)(J)4. of this rule do not apply to the following types of coatings and coating operations:
limits in paragraph (3)(J)2. of this rule do not apply to the following types of coatings and coating operations:
transparent substrates;
facturing installation while conducting performance tests on the coatings;
used in volumes less than fifty (50) gallons in any one (1) year, if substitute compliant coatings are not available, provided that the total usage of all such coatings does not exceed two hundred (200) gallons per year, per installation;
way cones;
one-half (0.5) millimeter thick (dried) and the area coated is less than twenty-five (25) square inches;
radio frequency interference (EMI/RFI) shielding coatings; and
(HBAC)-containing coatings applied to medical devices, provided that the total usage of all such coatings does not exceed one hundred (100) gallons per year, per installation.
cation equipment requirements in paragraph (3)(J)4. of this rule do not apply to airbrush operations using five (5) gallons or less per year of coating.
business machine plastic parts coatings, the VOC limits in paragraph (3)(J)2. of this rule do not apply to the following types of coatings and coating operations:
operations, the application equipment requirements in paragraph (3)(J)4. of this rule do not apply to extreme high gloss coatings.
coatings in subparagraph (3)(J)2.B. of this rule do not apply to coatings that meet the 10 CSR 10-5
following criteria:
equipment used for national defense;
to the successful operation of the military equipment;
ification or contract and a substitution of coatings that meet the VOC limits in subparagraph (3)(J)2.B. of this rule is prohibited; and
the use of the coating at the installation.
in subparagraph (3)(J)2.B. do not apply to pleasure craft touch-up and repair coatings supplied by the manufacturer or supplier in containers with a net volume of one (1) liter or less.
(K) Industrial Adhesive Application.
apply to adhesive application processes.
2. Emission limits.
owner or operator of an adhesive application process subject to this subsection may cause, allow, or permit the discharge into the ambient air of any VOCs in excess of the following, as delivered to the coating applicator(s): sive primers applied to particular substrates shall apply as follows:
specific VOC limit in subparagraph (3)(K)2.A., the specific limit is applicable rather than an adhesive-to-substrate limit; and
bond dissimilar substrates, the applicable substrate category with the highest VOC content shall be the limit.
ance. The emission limits in paragraph (3)(K)2. of this rule shall be achieved through one (1) of the following:
Determine the daily volume-weighted average VOC content of all coatings used in an adhesive application process, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds) per subparagraph (5)(C)3.A. of this rule. The adhesive application process is in compliance if this value is less than or equal to the emission limits in paragraph (3)(K)2. of this rule;
coatings and add-on controls. Calculate the required control system efficiency per paragraph (5)(C)4. of this rule. The adhesive application process is in compliance if the actual overall control system efficiency is greater than or equal to the required control system efficiency; or
is used to achieve compliance, the overall control system efficiency must be eighty-five percent (85%) or greater.
March 1, 2012, one (1) or a combination of the following equipment shall be used for adhesive application, unless achieving compliance by using an add-on control device per subparagraph (3)(K)3.C. of this rule:
including non-spray application methods similar to handor mechanically-powered caulking gun, brush, or direct hand application;
tion;
capable of achieving a transfer efficiency equivalent or better than achieved by HVLP spraying.
B. The VOC limits in subparagraph 2012, work practices shall be used to mini- (3)(K)2.A. of this rule for adhesives or adhemize VOC emissions from solvent storage, mixing operations, and handling operations for coatings, thinners, cleaning materials, and waste materials. Work practices shall include, but not be limited to, the following:
thinners, and cleaning materials in closed containers;
containers used for VOC-containing coatings, thinners, coating related waste, and cleaning materials are kept closed at all times except when depositing or removing these materials;
coatings, thinners, and cleaning materials;
cleaning materials in closed containers or pipes from one (1) location to another; and
cleaning of application, storage, mixing, and conveying equipment by ensuring that equipment cleaning is performed without atomizing the cleaning solvent and all spent solvent is captured in closed containers.
(4) Reporting and Record Keeping.
(A) The owner or operator of a surface coating unit covered under this rule shall keep records as necessary to determine compliance. Records kept should be appropriate for the facility, their products, and operations. These may include, as applicable, one (1) or more of the following:
VOC content as applied;
content for each coating type included in averaging for coating operations that achieve compliance through coating VOC content or a combination of coating VOC content and control system;
coating equipment cleaning; and
efficiency, control efficiency, and coating properties.
(C) Any owner or operator using an emission control device to achieve compliance shall maintain daily records of key system operating parameters for emission control equipment including, but not limited to:
control system used;
nance, including dates and duration of any outages;
coating unit employing a thermal or catalytic oxidizer to achieve compliance shall comply with the following requirements:
ing and recording equipment shall be installed and operated to accurately measure the operating temperature(s) for the control device; and
collected and recorded each day of operation of the surface coating unit and the control device:
time for the control device, monitoring equipment, and the associated surface coating unit;
(3)-hour periods of operation during which the average combustion temperature was more than fifty degrees Fahrenheit (50 ºF) below the average combustion temperature during the most recent emission test that demonstrated that the surface coating unit was in compliance; and
three (3)-hour periods of operation during which the average temperature of the exhaust gases immediately before the catalyst bed was more than fifty degrees Fahrenheit (50 ºF) below the average temperature of the exhaust gases during the most recent emission test that demonstrated that the surface coating unit was in compliance, and all three (3)-hour periods during which the average temperature difference across the catalyst bed was less than eighty percent (80%) of the average temperature difference during the most recent emission test that demonstrated that the surface coating operation was in compliance; and
coating unit employing a carbon adsorption system to achieve compliance shall comply with the following requirements:
and recording equipment shall be installed and operated for the carbon adsorption system:
ing and recording system that is capable of accurately measuring and recording the concentration of organic compounds in the exhaust gases from the carbon adsorption system;
equipment that is capable of accurately measuring and recording the total mass steam flow rate for each regeneration cycle of each carbon bed; and
equipment that is capable of accurately measuring and recording the temperature of each carbon bed after regeneration (and after completion of any cooling cycle(s)); and
collected and recorded each day of operation of the surface coating unit and the carbon adsorption system:
time for the carbon adsorption system, monitoring equipment, and the associated surface coating unit;
that employs a continuous emission monitoring and recording system to measure and record the concentration of organic compounds in the exhaust gases, all three (3)- hour periods of operation during which the average concentration level or reading in the exhaust gases is more than twenty percent (20%) greater than the exhaust gas organic compound concentration level or reading measured by the most recent performance test that demonstrated that the surface coating unit was in compliance;
tem that employs monitoring and recording equipment to measure and record the total mass steam flow rate for each regeneration cycle of each carbon bed, all carbon bed regeneration cycles during which the total mass steam flow rate was more than ten percent (10%) below the total mass steam flow rate during the most recent performance test that demonstrated that the surface coating unit was in compliance; and
tem that employs monitoring and recording equipment to measure and record the temperature of each carbon bed after regeneration (and after completion of any cooling cycle(s)) was more than ten percent (10%) greater than the carbon bed temperature during the most recent performance test that demonstrated that the surface coating unit was in compliance.
(5) Test Methods.
capture efficiency and control device efficiency, using the following test methods:
air streams shall be determined with a test consisting of three (3) separate runs, each lasting a minimum of sixty (60) minutes using one (1) of the following methods as specified by 40 CFR 60, Appendix A— Reference Methods:
Gaseous Organic Compound Emissions by Gas Chromatography;
Total Gaseous Non-methane Organic Emissions as Carbon; or
Total Gaseous Organic Concentration Using Flame Ionization Analyzer;
determined by using one (1) of the following methods as specified by 40 CFR 60, Appendix A—Reference Methods:
Traverses for Stationary Sources; or
Traverses for Stationary Sources with Small Stacks or Ducts;
shall be determined by using one (1) of the following methods as specified by 40 CFR 60, Appendix A—Reference Methods:
Stack Gas Velocity and Volumetric Flow Rate (Type S Pitot Tube);
of Gas Volume Through Pipes and Small Ducts;
Stack Gas Velocity and Volumetric Flow Rate in Small Stacks or Ducts (Standard Pitot Tube);
Volumetric Flow Rates in Small Pipes and Ducts;
Stack Gas Velocity and Volumetric Flow Rate With Three-Dimensional Probes;
Stack Gas Velocity and Volumetric Flow Rate With Two-Dimensional Probes; or
Stack Gas Velocity Taking Into Account Velocity Decay Near the Stack Wall;
method in 10 CSR 10-6.030(3);
gas, use the method in 10 CSR 10-6.030(4); and
the procedure in 10 CSR 10-6.030(20).
(B) Test Methods for Determining Coating Properties. The coating properties in paragraphs (5)(B)1. through (5)(B)6. of this rule shall be determined from the coating manufacturer’s supplied data or the method referenced in 10 CSR 10-6.030(14)(C). If there is a discrepancy between the manufacturer’s supplied data and the method referenced in 10 CSR 10-6.030(14)(C), compliance shall be based on the method referenced in 10 CSR 10-6.030(14)(C).
1. Density of coating, DC.
electrodeposition primer, the coating density shall be as received.
coatings, the coating density shall be as applied.
ing, VS.
electrodeposition primer, the volume fraction of solids in the coating shall be as received.
coatings, the volume fraction of solids in the coating shall be as applied.
in the coating, WE.
the coating, WO. This value does not include the weight fraction of water or exempt compounds.
electrodeposition primer, the weight fraction of VOC in the coating shall be as received.
coatings, the weight fraction of VOC in the coating shall be as applied.
ing, WS.
ing, WW.
(C) Other Test Methods and Calculations.
coating.
applied, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), shall be determined using Equation (1) as follows:
DC × WO
B = (1)
1− − ∑ ﴾DC × WW﴿ ﴾m DC × WEj﴿ 8.33 j=1 DEj
Where: B = VOC content of the coating as applied, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds); DC = density of coating as applied, expressed as pounds per gallon; WO = weight fraction of regulated VOC in the coating, as applied. This value does not include the weight fraction of water or exempt compounds; WW = weight fraction of water in the coating, as applied; WE = weight fraction of exempt compounds in the coating, as applied; DE = density of each exempt compound, expressed as pounds per gallon; m = number of exempt compounds in the coating; and 8.33 = density of water, expressed as pounds per gallon.
applied, expressed as pounds of VOC per gallon of coating solids, shall be determined using Equation (2) as follows:
DC × WO (2)
BS = VS
Where: BS = VOC content of the coating as applied, expressed as pounds of VOC per gallon of coating solids; DC = density of coating as applied, expressed as pounds per gallon; WO = weight fraction of regulated VOC in the coating, as applied. This value does not include the weight fraction of water or exempt compounds; and VS = volume fraction of solids in the coating, as applied.
applied, expressed as pounds of VOC per pound of coating solids, shall be determined using Equation (3) as follows:
DC × WO (3)
BMWS = DC × WS
Where: BMWS = VOC content of the coating as applied, expressed as pounds of VOC per pound of coating solids; DC = density of coating as applied, expressed as pounds per gallon; WO = weight fraction of regulated VOC in the coating, as applied. This value does not include the weight fraction of water or exempt compounds; and WS = weight fraction of solids in the coating, as applied.
limits expressed as pounds of VOC per gallon of coating (minus water and exempt compounds) shall be converted to an equivalent emission limit expressed as pounds of VOC per gallon of coating solids using Equation (4) as follows:
L (4)
LS = ﴾1− L ﴿ 7.36
Where: LS = emission limit expressed as pounds of VOC per gallon of coating solids; L = emission limit expressed as pounds of VOC per gallon of coating (minus water and exempt compounds); and 7.36 = average density of solvents, in pounds per gallon, used to originally establish the emission limits.
3. Weighted averaging.
age VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), shall be calculated using Equation (5) as follows:
n ∑ (Ai × Bi) i=1 (5)
DAVGVW = C
Where: DAVGVW = daily volume-weighted average VOC content, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds); A = daily gallons of each coating used (minus water and exempt compounds) in a surface coating unit; B = VOC content of the coating as applied, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds). This is determined by subparagraph (5)(C)1.A. of this rule; C = total daily gallons of coatings used (minus water and exempt compounds) in a surface coating unit; and n = number of coatings used in a surface coating unit.
VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating solids, shall be calculated using Equation (6) as follows: Specific to the St. Louis Metropolitan Area
n ) ∑ (ASi × BSi i=1 (6)
DAVGVWS = CS Where: DAVGVWS = daily volume-weighted average VOC content, expressed as pounds of VOC per gallon of coating solids; AS = daily gallons of coating solids for each coating used in a surface coating unit; BS = VOC content of the coating as applied, expressed as pounds of VOC per gallon of coating solids. This is determined by subparagraph (5)(C)1.B. of this rule; CS = total daily gallons of coatings solids used in a surface coating unit; and n = number of coatings used in a surface coating unit.
VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per pound of coating solids, shall be calculated using Equation (7) as follows:
n ) ∑ (AMWSi × BMWSi i=1 (7)
=
DAVGMWS CMWS
Where: DAVGMWS = daily mass-weighted average VOC content, expressed as pounds of VOC per pound of coating solids; AMWS = daily pounds of coating solids for each coating used in a surface coating unit; BMWS = VOC content of the coating as applied, expressed as pounds of VOC per pound of coating solids. This is determined by subparagraph (5)(C)1.C. of this rule; CMWS = total daily pounds of coatings solids used in a surface coating unit; and n = number of coatings used in a surface coating unit.
average VOC emission rate of an electrodeposition primer, expressed as pounds of VOC per gallon of coating solids deposited, shall be determined using Equation (8) as follows:
n m ∑ LCi DCi WOi + ∑ LDj DDj
MAVGVWS = i=1 j=1 × [1−E/100] n ∑ LCi VSi i=1 Where: MAVGVWS = monthly volume-weighted average VOC emission rate of the electrodeposition primer, expressed as pounds of VOC per gallon of coating solids deposited; LC = monthly volume of each coating consumed, as received, expressed as gallons; DC = density of each coating as received, expressed as pounds per gallon; WO = weight fraction of VOC in each coating, as received; LD = monthly volume of each type of VOC dilution solvent added to the coating, expressed as gallons; DD = density of each type of VOC dilution solvent added to the coating, expressed as pounds per gallon; VS = volume fraction of solids in each coating as received, expressed as gallons of solids per gallon of coating; E = overall control system efficiency; n = number of coatings used; and m = number of VOC dilution solvents used.
average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), shall be calculated using Equation (9) as follows:
n ∑ (Ai × Bi)
i=1 (9) =
MAVGVW C Where: MAVGVW = monthly volume-weighted average VOC content as applied, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds); A = monthly gallons of each coating used (minus water and exempt compounds) in a surface coating unit; B = VOC content of the coating as applied, expressed as pounds of VOC per gallon of coating (minus water and exempt compounds), as delivered to the coating applicator. This is determined by subparagraph (5)(C)1.A. of this rule;
C = total monthly gallons of coatings used (minus water and exempt compounds) in a surface coating unit; and n = number of coatings used in a surface coating unit.
cy shall be determined using Equation (10) as follows:
(DAVG − LS)
R = VWS ×100 (10) DAVGVWS
Where: R = required control system efficiency; DAVGVWS = daily volume-weighted average VOC content of all coatings used in a surface coating unit, expressed as pounds of VOC per gallon of coating solids, per subparagraph (5)(C)3.B. of this rule; and LS = emission limits expressed as pounds of VOC per gallon of coating solids, per paragraph (5)(C)2. of this rule.
AUTHORITY: section 643.050, RSMo Supp. 2010.* Original rule filed Dec. 15, 1978, effective July 12, 1979. Amended: Filed March 13, 1980, effective Sept. 12, 1980. Amended: Filed Aug. 15, 1983, effective Jan. 13, 1984. Amended: Filed Dec. 13, 1983, effective Jan. 13, 1984. Rescinded and readopted: Filed June 30, 1989, effective Nov. 26, 1989. Amended: Filed May 19, 2000, effective Jan. 30, 2001. Amended: Filed Nov. 30, 2010, effective Aug. 30, 2011. *Original authority: 643.050, RSMo 1965, amended 1972, 1992, 1993, 1995.