49 C.F.R. § 173.244
When § 172.101 of this subchapter specifies that a hazardous material be packaged under this section, only the following bulk packagings are authorized, subject to the requirements of subparts A and B of part 173 of this subchapter and the special provisions specified in column 7 of the § 172.101 table.
(a) Rail cars:
(1) Class DOT 105, 109, 112, 114, or 120 fusion-welded tank car tanks; and Class 106 or 110 multi-unit tank car tanks. For tank car tanks built prior to March 16, 2009, the following conditions apply:
(2) For materials poisonous by inhalation, until December 31, 2027, single unit tank car tanks built prior to March 16, 2009, and approved by the Tank Car Committee for transportation of the specified material. Except as provided in paragraph (a)(3) of this section, tank cars built on or after March 16, 2009, used for the transportation of the PIH materials listed below, must meet the applicable authorized tank car specification listed in the following table:
| Proper shipping name | Authorized tank carspecification |
|---|---|
| Acetone cyanohydrin, stabilized (Note 1) | 105H500W, 112H500W |
| Acrolein (Note 1) | 105H600W |
| Allyl Alcohol | 105H500W, 112H500W |
| Bromine | 105H500W |
| Chloropicrin | 105H500W, 112H500W |
| Chlorosulfonic acid | 105H500W, 112H500W |
| Dimethyl sulfate | 105H500W, 112H500W |
| Ethyl chloroformate | 105H500W, 112H500W |
| Hexachlorocyclopentadiene | 105H500W, 112H500W |
| Hydrocyanic acid, aqueous solution or Hydrogen cyanide, aqueous solution with not more than 20% hydrogen cyanide (Note 2) | 105H500W, 112H500W |
| Hydrogen cyanide, stabilized (Note 2) | 105H600W |
| Hydrogen fluoride, anhydrous | 105H500W, 112H500W |
| Poison inhalation hazard, Zone A materials not specifically identified in this table | 105H600W |
| Poison inhalation hazard, Zone B materials not specifically identified in this table | 105H500W, 112H500W |
| Phosphorus trichloride | 105H500W, 112H500W |
| Sulfur trioxide, stabilized | 105H500W, 112H500W |
| Sulfuric acid, fuming | 105H500W, 112H500W |
| Titanium tetrachloride | 105H500W, 112H500W |
| Note 1 to table 1 to paragraph (a)(2): Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). Restenciling to a lower test pressure is not authorized. | |
| Note 2 to table 1 to paragraph (a)(2): Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 15.51 Bar (225 psig). Restenciling to a lower test pressure is not authorized. |
(3) As an alternative to the authorized tank car specification listed in the table in paragraph (a)(2) of this section, a car of the same authorized tank car specification but of the next lower test pressure, as prescribed in column 5 of the table at § 179.101-1 of this subchapter, may be used provided that both of the following conditions are met:
[Amdt. 173-224, 55 FR 52663, Dec. 21, 1990, as amended at 56 FR 66275, Dec. 20, 1991; 57 FR 45463, Oct. 1, 1992; Amdt. 173-252, 61 FR 28676, June 5, 1996; 68 FR 45037, July 31, 2003; 72 FR 55693, Oct. 1, 2007; 74 FR 1799, Jan. 13, 2009; 85 FR 75714, Nov. 25, 2020; 87 FR 79779, Dec. 27, 2022]