N.Y. Comp. Codes R. & Regs. tit. 20, § 561.7
(b) Purchasers of a large volume of motor fuel shall give the seller a certificate in such form as the Department of Taxation and Finance may prescribed indicating whether the fuel is being purchased for resale or purchased at retail for the purchaser's own use. Where the purchaser of a large volume of motor fuel does not provide the seller with such a certificate, the seller must determine whether the prepaid tax which would be due on each gallon of motor fuel if the fuel purchased for resale or the retail sales tax which would be due on each gallon of motor fuel if the fuel was purchased at retail is greater. If the prepaid tax is greater, the seller shall treat the purchase as a purchase for resale, pass through the prepaid tax and issue a certification of tax payment as provided in section 561.5 of this Part. If the retail sales tax is greater, the seller shall treat the purchase as purchase at retail and collect the sales tax. For purposes of this subdivision, a purchase of a large volume of motor fuel is a purchase of 500 gallons or more.
(1) Retail sales of motor fuel to the following purchasers in the described circumstances are exempt from sales tax:
(vi) diplomatic missions and diplomatic personnel purchasing motor fuel with credit cards issued by oil companies, as provided in section 529.5(i) of this Title.
Only purchasers who fall within the categories listed above may purchase motor fuel at retail without payment of the sales tax to the vendor. The other exemptions from sales tax provided for by sections 1115 and 1116 of the Tax Law do not apply to sales of motor fuel. Although these sales are not exempt under these other exemption provisions, refunds and credits are allowed. See section 561.10(c) of this Part.
(2) In order to make retail purchases of motor fuel without payment of tax, a purchaser listed in paragraph (1) of this subdivision must furnish to the seller either:
(3) Sales of motor fuel at retail—presumptions.
(iii) When a vendor makes a sale of motor fuel which is exempt as provided in paragraph (1) of this subdivision, as proof of the exemption the vendor shall obtain from the purchaser and retain in his files either:
(c) Exempt sales.