N.H. Code Admin. R. Env-Wq 809.06 – Testing: Constituents Required For All QC Sludge

(a) Subject to (b), below, sludge samples collected pursuant to Env-Wq 809.05 or Env-Wq 809.07 shall be analyzed for the constituents listed in Table 809-2, below, in accordance with the methods specified.
(b) Testing for enteric viruses as specified in Table 809-2, section G shall be required only for generators of class B biosolids requesting certification of the biosolids for reclamation uses.
(c) The constituents required to be analyzed shall be as follows:
Table 809-2: Compounds, Chemical Abstract Service Registration Number (CAS),
Analytical Methods, and Detection Limits
#
Compound
CAS
Analytical Method
Detection Limit (mg/kg)
Section A. Volatile Organic Compounds
1
Dichlorodifluoromethane
75-71-8
SW846 - 8000 series
2.0
2
Chloromethane
74-87-3
SW846 - 8000 series
2.0
3
Vinyl chloride
75-01-4
SW846 - 8000 series
2.0
4
Bromomethane
74-83-9
SW846 - 8000 series
2.0
5
Chloroethane
75-00-3
SW846 - 8000 series
2.0
6
Trichlorofluoromethane
75-69-4
SW846 - 8000 series
2.0
7
Diethyl ether
60-29-7
SW846 - 8000 series
2.0
8
Acetone
67-64-1
SW846 - 8000 series
10.0
9
1,1-Dichloroethene
75-35-4
SW846 - 8000 series
2.0
10
Methylene chloride
75-09-2
SW846 - 8000 series
2.0
11
Carbon disulfide
75-15-0
SW846 - 8000 series
2.0
12
Methyl-tert-butylether (MTBE)
1634-04-4
SW846 - 8000 series
2.0
13
trans-1,2-Dichloroethene
156-60-5
SW846 - 8000 series
2.0
14
1,1-Dichloroethane
75-34-3
SW846 - 8000 series
2.0
15
2-Butanone (MEK)
78-93-3
SW846 - 8000 series
10.0
16
2,2-Dichloropropane
590-20-7
SW846 - 8000 series
2.0
17
cis-1,2-Dichloroethene
156-59-2
SW846 - 8000 series
2.0
18
Chloroform
67-66-3
SW846 - 8000 series
2.0
19
Bromochloromethane
74-97-5
SW846 - 8000 series
2.0
20
Tetrahydrofuran (THF)
109-99-9
SW846 - 8000 series
10.0
21
1,1,1-Trichloroethane
71-55-6
SW846 - 8000 series
2.0
22
1,1-Dichloropropene
563-58-6
SW846 - 8000 series
2.0
23
Carbon tetrachloride
56-23-5
SW846 - 8000 series
2.0
24
1,2-Dichloroethane
107-06-2
SW846 - 8000 series
2.0
25
Benzene
71-43-2
SW846 - 8000 series
2.0
26
Trichloroethene
79-01-6
SW846 - 8000 series
2.0
27
1,2 Dichloropropane
78-87-5
SW846 - 8000 series
2.0
28
Dichlorobromomethane
75-27-4
SW846 - 8000 series
2.0
29
Dibromomethane
74-95-3
SW846 - 8000 series
2.0
30
4-Methyl-2-pentanone (MIBK)
108-10-1
SW846 - 8000 series
10.0
31
Cis-1,3-Dichloropropene
10061-01-5
SW846 - 8000 series
2.0
32
Toluene
108-88-3
SW846 - 8000 series
2.0
33
trans-1,3-Dichloropropene
10061-02-6
SW846 - 8000 series
2.0
34
1,1,2-Trichloroethane
79-00-5
SW846 - 8000 series
2.0
35
2-Hexanone
591-78-6
SW846 - 8000 series
10.0
36
1,3-Dichloropropane
142-28-9
SW846 - 8000 series
2.0
37
Tetrachloroethene
127-18-4
SW846 - 8000 series
2.0
38
Dibromochloromethane
128-48-1
SW846 - 8000 series
2.0
39
1,2-Dibromoethane
106-93-4
SW846 - 8000 series
2.0
40
Chlorobenzene
108-90-7
SW846 - 8000 series
2.0
41
1,1,1,2-Tetrachloroethane
630-20-6
SW846 - 8000 series
2.0
42
Ethylbenzene
100-41-4
SW846 - 8000 series
2.0
43
m&p-Xylene
108-38-3
106-42-3
SW846 - 8000 series
2.0
44
o-Xylene
95-47-6
SW846 - 8000 series
2.0
45
Styrene
100-42-5
SW846 - 8000 series
2.0
46
Bromoform
75-25-2
SW846 - 8000 series
2.0
47
Isopropylbenzene
98-82-8
SW846 - 8000 series
2.0
48
1,1,2,2-Tetrachloroethane
79-34-5
SW846 - 8000 series
2.0
49
1,2,3-Trichloropropane
96-18-4
SW846 - 8000 series
2.0
50
n-Propylbenzene
98-06-6
SW846 - 8000 series
2.0
51
Bromobenzene
108-86-1
SW846 - 8000 series
2.0
52
1,3,5-Trimethylbenzene
108-67-8
SW846 - 8000 series
2.0
53
2-Chlorotoluene
95-49-8
SW846 - 8000 series
2.0
54
4-Chlorotoluene
106-43-4
SW846 - 8000 series
2.0
55
tert-Butylbenzene
104-51-8
SW846 - 8000 series
2.0
56
1,2,4-Trimethylbenzene
95-63-6
SW846 - 8000 series
2.0
57
sec-Butylbenzene
135-98-8
SW846 - 8000 series
2.0
58
p-Isopropyltoluene
99-87-6
SW846 - 8000 series
2.0
59
1,3-Dichlorobenzene
541-73-1
SW846 - 8000 series
2.0
60
1,4-Dichlorobenzene
106-46-7
SW846 - 8000 series
2.0
61
n-Butylbenzene
104-51-8
SW846 - 8000 series
2.0
62
1,2-Dichlorobenzene
95-50-1
SW846 - 8000 series
2.0
63
1,2-Dibromo-3-chloropropane
96-12-8
SW846 - 8000 series
2.0
64
1,2,4-Trichlorobenzene
120-82-1
SW846 - 8000 series
2.0
65
Hexachlorobutadiene
87-68-3
SW846 - 8000 series
2.0
66
Naphthalene
91-20-3
SW846 - 8000 series
2.0
67
1,2,3-Trichlorobenzene
87-61-6
SW846 - 8000 series
2.0
Section B. Semi-volatile Compounds
68
1,2-Diphenylhydrazine (as Azobenzene)
122-66-7
SW846 - 8000 series
2.5
69
2,4,5-Trichlorophenol
95-95-4
SW846 - 8000 series
2.5
70
2,4,6-Trichlorophenol
88-06-2
SW846 - 8000 series
2.5
71
2,4-Dichlorophenol
120-83-2
SW846 - 8000 series
2.5
72
2,4-Dimethylphenol
105-67-9
SW846 - 8000 series
2.5
73
2,4-Dinitrophenol
51-28-5
SW846 - 8000 series
25.0
74
2,4-Dinitrotoluene
121-14-2
SW846 - 8000 series
2.5
75
2,6-Dinitrotoluene
606-20-2
SW846 - 8000 series
2.5
76
2-Chloronaphthalene
91-59-7
SW846 - 8000 series
2.5
77
2-Chlorophenol
95-97-8
SW846 - 8000 series
2.5
78
2-Methylnaphthalene
91-57-6
SW846 - 8000 series
2.5
79
2-Methylphenol (o-Cresol)
95-48-7
SW846 - 8000 series
5.0
80
2-Nitroaniline
88-74-4
SW846 - 8000 series
5.0
81
2-Nitrophenol
88-75-5
SW846 - 8000 series
5.0
82
3,3'-Dichlorobenzidine
91-94-1
SW846 - 8000 series
10.0
83
3-Nitroaniline
99-09-2
SW846 - 8000 series
5.0
84
3&4-Methylphenol (m&p-Cresol)
106-44-5
SW846 - 8000 series
5.0
85
4,6-Dinitro-2-methylphenol
534-52-1
SW846 - 8000 series
20.0
86
4-Bromophenyl phenylether
85-68-7
SW846 - 8000 series
10
87
4-Chloro-3-methylphenol
59-50-7
SW846 - 8000 series
10
88
4-Chloroaniline
106-47-8
SW846 - 8000 series
2.5
89
4-Chlorophenyl phenylether
7005-72-3
SW846 - 8000 series
10
90
4-Nitroaniline
100-01-6
SW846 - 8000 series
5.0
91
4-Nitrophenol
100-02-7
SW846 - 8000 series
12
92
Acenaphthene
83-32-9
SW846 - 8000 series
5.0
93
Acenaphthylene
208-96-8
SW846 - 8000 series
5.0
94
Anthracene
120-12-7
SW846 - 8000 series
5.0
95
Benzidine
92-87-5
SW846 - 8000 series
25.0
96
Benzo (a) anthracene
56-55-3
SW846 - 8000 series
2.5
97
Benzo (a) pyrene
50-32-8
SW846 - 8000 series
2.5
98
Benzo (b) fluoranthene
205-99-2
SW846 - 8000 series
2.5
99
Benzo (g,h,i) perylene
191-24-2
SW846 - 8000 series
2.5
100
Benzo (k) fluoranthene
207-08-9
SW846 - 8000 series
2.5
101
Bis (2-chloroethoxy) methane
111-91-1
SW846 - 8000 series
5.0
102
Bis (2-chloroethyl) ether
111-44-4
SW846 - 8000 series
2.5
103
Bis (2-chloroisopropyl) ether
39638-32-9
SW846 - 8000 series
2.0
104
Bis (2-ethylhexyl) phthalate
117-81-7
SW846 - 8000 series
5.0
105
Butyl Benzyl phthalate
85-68-7
SW846 - 8000 series
5.0
106
Carbazole
86-74-8
SW846 - 8000 series
2.5
107
Chrysene
218-01-9
SW846 - 8000 series
2.5
108
Di-n-butyl phthalate
84-74-2
SW846 - 8000 series
5.0
109
Di-n-octyl phthalate
117-84-0
SW846 - 8000 series
5.0
110
Dibenzo (a,h) anthracene
53-70-3
SW846 - 8000 series
2.5
111
Dibenzofuran
132-64-9
SW846 - 8000 series
2.5
112
Diethyl phthalate
84-66-2
SW846 - 8000 series
5.0
113
Dimethyl phthalate
131-11-3
SW846 - 8000 series
5.0
114
Fluoranthene
206-44-0
SW846 - 8000 series
2.5
115
Fluorene
86-73-7
SW846 - 8000 series
2.5
116
Hexachlorobenzene
118-74-1
SW846 - 8000 series
2.5
117
Hexachlorocyclopentadiene
77-47-4
SW846 - 8000 series
5.0
118
Hexachloroethane
67-72-1
SW846 - 8000 series
2.5
119
Indeno (1,2,3-cd) pyrene
193-39-5
SW846 - 8000 series
2.5
120
Isophorone
78-59-1
SW846 - 8000 series
2.5
121
N-Nitroso-di-n-propylamine
621-64-7
SW846 - 8000 series
2.5
122
N-Nitrosodimethylamine
62-75-9
SW846 - 8000 series
5.0
123
N-Nitrosodiphenylamine
86-30-6
SW846 - 8000 series
2.5
124
Nitrobenzene
98-95-3
SW846 - 8000 series
2.5
125
Pentachlorophenol
87-86-5
SW846 - 8000 series
5.0
126
Phenanthrene
85-01-8
SW846 - 8000 series
2.5
127
Phenol
108-95-2
SW846 - 8000 series
5.0
128
Pyrene
129-00-0
SW846 - 8000 series
2.5
Section C. Metals
129
Total Arsenic
7440-38-2
SW846 6000/7000 series
10
130
Total Cadmium
7440-43-9
SW846 6000/7000 series
1.0
131
Total Chromium
16065-83-1
SW846 6000/7000 series
10
132
Total Copper
7440-50-8
SW846 6000/7000 series
10
133
Total Lead
7439-92-1
SW846 6000/7000 series
11
134
Total Mercury
7439-97-6
SW846 7000 series
0.05
135
Total Molybdenum
7439-98-7
SW846 6000/7000 series
10
136
Total Nickel
7440-02-0
SW846 6000/7000 series
10
137
Total Selenium
7782-49-2
SW846 6000/7000 series
18
138
Total Zinc
7440-66-6
SW846 6000/7000 series
10
139
Total Antimony
7440-36-0
SW846 6000/7000 series
8.0
140
Total Beryllium
7440-41-7
SW846 6000/7000 series
0.1
141
Total Silver
7440-22-4
SW846 6000/7000 series
4.0
142
Total Thallium
7440-28-0
SW846 6000/7000 series
10
Section D. Polychlorinated Biphenyls
143
PCB-1242
53469-21-9
SW846 - 8000 series
0.7
144
PCB-1254
11097-69-1
SW846 - 8000 series
0.7
145
PCB-1221
11104-28-2
SW846 - 8000 series
0.7
146
PCB-1232
11141-16-5
SW846 - 8000 series
0.7
147
PCB-1248
12672-29-6
SW846 - 8000 series
0.7
148
PCB-1260
11096-82-5
SW846 - 8000 series
0.7
149
PCB-1016
12674-11-2
SW846 - 8000 series
0.7
Section E. Additional Analyses
150
pH
not applicable (na)
SM-4500-H
na
151
Percent solids
na
SM-2540 G
na
152
nitrate-nitrite
14797-55-8
14797-65-0
SM-4500-NO₃
SW846 - 9210
EPA 353 -3000 series
30
153
Total Kjeldalh nitrogen
na
SM-4500-N_org
EPA-351.3
300
154
ammonia nitrogen
na
SM-4500-NH₃
EPA-350
30
155
Total organic nitrogen
na
calculation
na
156
potassium
na
SM-3500-K
SW846 6000/7000 series
15
157
phosphorus
na
SM-4500-P
EPA-365
15
Section F. Dioxins
158
Total Toxic Equivalent,
2,3,7,8 TCDD
1746-01-6
EPA 1613
5 ppt TEQ
Section G. Enteric Virus
159
Enteric Virus
na
ASTM D4994-89 (2002)
1 PFU/ 4 grams
(d) The following shall apply to Table 809-2:
1. (1) Subject to (2) and (3), below, the detection limit for all the analyses shall be at or below the detection limits specific in Table 809-2;
2. (2) If the percent solids in a sludge is below 5%, the results shall be reported in mg/L and the detection limits shall be appropriate to the methodology specified in Table 809-2 for a water matrix; and
3. (3) If the detection limit specified in Table 809-2 cannot be achieved by the methodology listed, the department shall accept the detection limits that are routinely achievable.

Source. (See Revision Note #1 and Revision Note #2 at chapter heading for Env-Wq 800) #10998, eff 1-1-16