Cal. Code Regs. tit. 17, § 95153
(a) Metered Natural Gas Pneumatic Device and Pneumatic Pump Venting. The operator of a facility who is subject to the requirements of sections 95153(a) and (b) must calculate emissions from a natural gas powered continuous high bleed control device and pneumatic pump venting using the method specified in paragraph (a)(1) below when the natural gas flow to the device is metered. By January 1, 2015, natural gas consumption must be metered for all of the operator's pneumatic continuous high bleed devices and pneumatic pumps. The operator may choose to also meter flow to any or all low bleed and intermittent bleed natural gas powered devices. By January 1, 2019, all continuous bleed pneumatic devices must meet the accuracy requirements of section 95103(k) by installation of metering or by measuring, at least annually, the volume of natural gas emitted in cubic feet per hour using a temporary meter, or calibrated bag, or high volume sampler according to the methods set forth in sections 95154(b), (c), and (d) respectively. The operator must calculate the annual natural gas volumetric emissions at standard conditions using calculations in paragraph (r) of this section and calculate both CH4 and CO2 volumetric and mass emissions from volumetric natural gas emissions using the calculations in paragraphs (s) and (t) of this section. For unmetered devices the operator must use the method specified in section 95153(b). Vented emissions from natural gas driven pneumatic pumps covered in paragraph (d) of this section do not have to be reported under paragraph (a) of this section.
(1) The operator must calculate vented emissions for all metered natural gas powered pneumatic devices and pumps using the following equation:
)
(Eq. 1)
Where:
Em = Annual natural gas emissions at standard conditions, in cubic feet, for all metered natural gas powered pneumatic devices.
n = Total number of meters.
Bn = Natural gas consumption for meter n.
(b) Non-metered Natural Gas Pneumatic Device Venting. Through calendar year 2018, the operator must calculate CH4 and CO2 emissions from all un-metered natural gas powered pneumatic intermittent bleed and continuous low and high bleed devices using the following method:
)
(Eq. 2)
Where:
Enm,i,x = Annual natural gas emissions at standard conditions for all unmetered natural gas powered devices and pumps (in scf).
i = Total number of unmetered component types.
x = Total number of component type i.
EFi = Population emission factor for natural gas pneumatic device type i (scf/hour/component) listed in Tables 1A, 3, and 4 of Appendix A for onshore petroleum and natural gas production, onshore natural gas transmissions compression, and underground natural gas facilities, respectively.
Ti,x = Total number of hours type i component x was in service. Default is 8760 hours; or 8784 for a leap year.
(c) Acid gas removal (AGR) vents. For AGR vents (including processes such as amine, membrane, molecular sieve or other absorbents and adsorbents), the operator must calculate emissions for CO2 only (not CH4) vented directly to the atmosphere or emitted through a flare, engine (e.g. permeate from a membrane or de-adsorbed gas from a pressure swing adsorber used as fuel supplement), or sulfur recovery plant using the applicable calculation methodologies described in paragraphs (c)(1)-(c)(10) below.
(2) Calculation Methodology 2. If CEMS is not available but a vent meter is installed, the operator must use the CO2 composition and annual volume of vent gas to calculate emissions using Equation 3 of this section.
Eα,CO2 = Vs * VolCO2
(Eq. 3)
Where:
Ea,CO2 = Annual volumetric CO2 emissions at actual conditions, in cubic feet per year.
Vs = Total annual volume of vent gas flowing out of the AGR unit in cubic feet per year at actual conditions as determined by flow meter using methods set forth in section 95154(b). Alternatively, the facility operator may follow the manufacturer's instructions for calibration of the vent meter.
VolCO2 = Annual average volumetric fraction of CO2 content in the vent gas out of the AGR unit as determined in (c)(5) of this section.
(3) Calculation Methodology 3. If CEMS or a vent meter is not installed, the operator may use the inlet or outlet gas flow rate of the acid gas removal unit to calculate emissions for CO2 using Equations 4A or 4B of this section. If inlet gas flow rate is known, use Equation 4A. If outlet gas flow rate is known, use Equation 4B.
Eα,CO2 = Vin * [(VolI - VolO)/(1-VolO)]
(Eq. 4A)
Eα,CO2 = Vout * [(VolI - VolO)/(1-VolI)]
(Eq. 4B)
Where:
Eα,CO2= Annual volumetric CO2 emissions at actual conditions, in cubic feet per year.
Vin= Total annual volume of natural gas flow into the AGR unit in cubic feet per year at actual condition as determined using methods specified in paragraph (c)(4) of this section.
Vout= Total annual volume of natural gas flow out of the AGR unit in cubic feet per year at actual condition as determined using methods specified in paragraph (c)(4) of this section.
VolI= Volume fraction of CO2 content in natural gas into the AGR unit as determined in paragraph (c)(6) of this section.
Volo= Volume fraction of CO2 content in natural gas out of the AGR unit as determined in paragraph (c)(7) of this section.
(7) Determine volume fraction of CO2 content in natural gas out of the AGR unit using one of the methods specified in paragraph (c)(7) of this section.
(d) Dehydrator vents. For dehydrator vents, calculate annual CH4, CO2, and N2O emissions using any of the calculation methodologies described in paragraph (d) of this section.
(1) Calculate annual mass emissions from dehydrator vents using a software program which applies the Peng-Robinson equation of state (Equation 38 of section 95154) to calculate the equilibrium coefficient, speciates CH4 and CO2 emissions from dehydrators, and has provisions to include regenerator control devices, a separator flash tank, stripping gas and a gas injection pump or gas assist pump. A minimum of the following parameters determined by engineering estimate based on best available data must be used to characterize emissions from dehydrators.
(K) Wet natural gas composition. Determine this parameter by selecting one of the methods described in subparagraphs (1) - (4) below.
(3) Calculate annual emissions from dehydrator vents to flares or regenerator fire-box/fire tubes as follows:
(4) In the case of dehydrators that use desiccant, operators must calculate emissions from the amount of gas vented from the vessel when it is depressurized for the desiccant refilling process using Equation 5 of this section.
Es,n = n(H * D2 * Π * % G * P2/(4 * P1))
(Eq. 5)
Where:
ES,n = Annual natural gas emissions at standard conditions in cubic feet.
n = number of fillings in reporting period.
H = Height of the dehydrator vessel (ft).
D = Inside diameter of the vessel (ft).
Π = pi (3.1416).
%G = Percent of packed vessel volume that is gas (expressed as a decimal, e.g.,15% = 0.15).
P1 = Atmospheric pressure (psia).
P2 = Pressure of the gas (psia).
(e) Well venting for liquids unloadings. Calculate CO2 and CH4 emissions from well venting for liquids unloading using one of the calculation methodologies described in paragraphs (e)(1), (e)(2) or (e)(3) of this section.
(1) Calculation Methodology 1. Calculate the total emissions for well venting for liquids unloading without plunger lift assist using Equation 6 of this section.
)
(Eq. 6)
Where:
ES,n = Annual natural gas emissions at standard conditions, in cubic feet/year.
W = Total number of well venting events for liquids unloading for each basin.
0.37x10-3 = {3.14(pi)/4}/{14.7x144}(psia converted to pounds per square feet).
p = wells 1 through W with well venting for liquids unloading in the basin.
CDp = Casing diameter for each well, p, in inches.
WDp = Well depth from either the top of the well or the lowest packer to the bottom of the well, for each well, p, in feet.
SPp = For each well, p, shut-in pressure or surface pressure for wells with tubing production and no packers or casing pressure for each well, p, in pounds per square inch absolute (psia).
Vp = Number of unloading events per year per well, p.
SFRp = Average flow-line rate of gas for well p, at standard conditions in cubic feet per hour. Use Equation 29 to calculate the average flow-rate at standard conditions.
HRp,q = Hours that each well, p, was left open to the atmosphere during each unloading event, q.
1.0 = Hours for average well to blowdown casing volume at shut-in pressure.
Zp,q = If HRp,q is less than 1.0 then Zp,q is equal to 0. If HRp,q is greater than or equal to 1.0 then Zp,q is equal to 1.
(2) Calculation Methodology 2. Calculate emissions from each well venting to the atmosphere for liquids unloading with plunger lift assist using Equation 7 of this section.
)
(Eq. 7)
Where:
ES,n = Annual natural gas emissions at standard conditions, in cubic feet/year.
W = Total number of well venting liquid unloading events at wells using plunger lift assist technology for each basin.
0.37 x 10-3 = {3.14(pi)/4}/{14.7 x 144} (psia converted to pounds per square feet).
TDp = Tubing internal diameter for each well, p, in inches.
WDp = Tubing depth to plunger bumper for each well, p, in feet.
SPp = Flow-line pressure for each well, p, in pounds per square inch absolute (psia).
Vp = Number of unloading events per year for each well, p.
SFRp = Average flow-line rate of gas for well, p, at standard conditions in cubic feet per hour. Use Equation 29 to calculate the average flow-line rate at standard conditions.
HRp,q = Hours that each well, p, was left open to the atmosphere during each unloading, q.
0.5 = Hours for average well to blowdown tubing volume at flow-line pressure.
Zp,q = If HRp,q is less than 0.5, then Zp,q is equal to 0. If HRp,q is greater than or equal to 0.5, then Zp,q is equal to 1.
(f) Gas well venting during well completions and well workovers. Using one of the calculation methodologies in this paragraph (f)(1) through (f)(5) below, operators must calculate CH4, CO2 and N2O (when flared) annual emissions from gas well venting during both conventional completions and completions involving hydraulic fracturing in wells and during both conventional well workovers and well workovers involving hydraulic fracturing.
(1) Calculation Methodology 1. Measure total gas flow with a recording flow meter (analog or digital) installed in the vent line ahead of a flare or vent id used. The facility operator must correct total gas volume vented for the volume of CO2 or N2:
Eα = VM - VCO2 or N2
(Eq. 8)
Where:
Ea = Gas emissions during the well completion or workover at actual conditions (m3).
VM= Volume of vented gas measured during well completion or workover (m3).
VCO2 or N2 = Volume of CO2 or N2 injected during well completion or workover (m3).
(2) Calculation Methodology 2.
(D) Calculate the average flow rate during sonic conditions using Equation 9 of this section.
)
(Eq. 9)
Where:
FRa = Average flow rate in cubic feet per hour, under actual sonic flow conditions.
A = Cross sectional open area of the restriction orifice (m2).
Tu = Upstream temperature (degrees Kelvin).
187.08 = Constant with units of m2/(sec2x K).
1.27 x 105 = Conversion from m3/second to ft3/hour.
(E) Calculate total gas volume vented during sonic flow conditions as follows:
VS = FRa * TS
(Eq. 10)
Where:
Vs = Volume of gas vented during sonic flow conditions (scf).
TS = Length of time that the well vented under sonic conditions (hours).
(F) For each of the sets of data points (Tu, P1, P2, and elapsed time under subsonic flow conditions) recorded as the well vented under subsonic flow conditions, calculate the instantaneous gas flow rate as follows:
)
(Eq. 11)
Where:
FRa = Instantaneous flow rate in cubic feet per hour, under actual subsonic flow conditions.
A = Cross sectional open area of the restriction orifice (m2).
P1 = Upstream pressure (psia).
Tu = Upstream temperature (degrees Kelvin).
P2 = Downstream pressure (psia).
3430 = Constant with units of m2/(sec2xK).
1.27 x 105 = Conversion from m3/second to ft3/hour.
(I) Sum the vented volumes during subsonic and sonic flow and adjust vented emissions for the volume of CO2 and N2 injected and the volume of gas recovered to a sales line as follows:
)
(Eq. 12)
Where:
Es = Total volume of gas vented during the well completion or workover (scf).
Vs = Volume of gas vented during sonic flow conditions for the well completion or workover (scf) (see Eq. 10).
Vss = Volume of gas vented during subsonic flow conditions for the well completion or workover (scf) (see 95153(f)(2)(G) above).
VCO2/N2 = Volume of CO2 or N2 injected during the well completion or workover (scf).
VSG = Volume of gas recovered to a sales line during the well completion or workover (scf).
(3) The volume of CO2 or N2 injected into the well reservoir during energized hydraulic fractures must be measured using an appropriate meter as described in section 95154(b) or using receipts of gas purchases that are used for the energized fracture job.
(4) Determine if the backflow gas from the well completion or workover is recovered with purpose designed equipment that separates natural gas from the backflow, and sends this natural gas to a flow-line (e.g., reduced emissions completion or workover).
(g) Equipment and pipeline blowdowns. Calculate CO2 and CH4 blowdown emissions from depressurizing equipment and natural gas pipelines to reduce system pressure for planned or emergency shutdowns resulting from human intervention or to take equipment out of service for maintenance (excluding depressurizing to a flare, over-pressure relief, operating pressure control venting and blowdown of non-GHG gases; desiccant dehydrator blowdown venting before reloading is covered in paragraphs (d)(4) of this section) as follows:
(2) Calculate the total annual venting emissions for unique volumes using either Equation 13 or 14 of this section.
)
(Eq. 13)
Where:
Es,n = Annual natural gas venting emissions at standard conditions from blowdowns in cubic feet.
N = Number of occurrences of blowdowns for each unique physical volume in the calendar year.
V = Unique physical volume (including pipelines, compressors and vessels) between isolation valves in cubic feet.
C = Purge factor that is 1 if the unique physical volume is not purged or zero if the unique physical volume is purged using non-GHG gases.
Ts = Temperature at standard conditions (60°F).
Ta = Temperature at actual conditions in the unique physical volume (°F).
Ps = Absolute pressure at standard conditions (14.7 psia).
Pa = Absolute pressure at actual conditions in the unique physical volume (psia).
)
(Eq. 14)
Where:
Es,n = Annual natural gas venting emissions at standard conditions from blowdowns in cubic feet.
PV = Number of unique physical volumes blowndown.
N = Number of occurrences of blowdowns for each unique physical volume.
V = Total physical volume (including pipelines, compressors and vessels) between isolation valves in cubic feet for each blowdown “p”.
Ts = Temperature at standard conditions (60°F).
Ta,p = Temperature at actual conditions in the unique physical volume (°F).
Ps = Absolute pressure at standard conditions (14.7 psia).
Pa,b,p = Absolute pressure at actual conditions in the unique physical volume (psia) at the beginning of the blowdown “p”.
Pa,e,p = Absolute pressure at actual conditions in the unique physical volume (psia) at the end of the blowdown “p”; 0 if blowdown volume is purged using non-GHG gases.
(h) Dump Valves. Calculate emissions from occurrences of gas-liquid separator liquid dump valves not closing during the calendar year by using the method found in 95153(i).
(i) Transmission storage tanks. For vent stacks connected to one or more transmission condensate storage tanks, either water or hydrocarbon, without vapor recovery, in onshore natural gas transmission compression and onshore petroleum and natural gas production, the operator of a facility must calculate CH4, CO2 and N2O annual emissions from condensate scrubber dump valve leakage as follows:
(2) If the tank vapors from the vent stack are continuous for five minutes, or the acoustic leak detection device detects a leak, then use one of the following two methods in paragraph (i)(2) of this section to quantify annual emissions:
(4) Calculate annual emissions from storage tanks to flares as follows:
(j) Well testing venting and flaring. Calculate CH4, CO2 and N2O (when flared) gas and oil well testing venting and flaring emissions as follows:
(2) If total GOR cannot be determined from available data, then the facility operator must measure quantities reported in this section according to one of the two procedures in paragraph (j)(2) of this section to determine total GOR.
(3) Estimate venting emissions using Equation 15 (for oil wells) or Equation 16 (for gas wells) of this section.
ES,n = Total GOR * FR * D
(Eq.15)
Eα,n = PR * D
(Eq.16)
Where:
ES,n = Annual volume of gas emissions from well(s) testing in standard cubic feet.
Ea,n = Annual volumetric natural gas emissions from well(s) testing in cubic feet under actual conditions.
Total GOR = Gas-to-oil ratio, for well p in basin q, in standard cubic feet of gas per barrel of oil; oil here refers to hydrocarbon liquids produced of all API gravities.
FR = Annual average flow rate in barrels of oil per day for the oil well(s) being tested.
PR = Average annual production rate in actual cubic feet per day for the gas well(s) being tested.
D = Number of days during the year the well(s) is tested.
(6) Calculate emissions from well testing to flares as follows:
(k) Associated gas venting and flaring. Calculate CH4, CO2 and N2O (when flared) associated gas venting and flaring emissions not in conjunction with well testing as follows:
(2) If total GOR cannot be determined from available data, then use one of the two procedures in paragraph (k)(2) of this section to determine total GOR.
(3) Estimate venting emissions using Equation 17 of this section.
)
(Eq. 17)
Where:
Ea,n = Annual volumetric natural gas emissions, at the facility level, from associated gas venting in standard cubic feet.
Total GORp,q = Gas-to-oil ratio, for well p in basin q, in standard cubic feet of gas per barrel of oil; oil here refers to hydrocarbon liquids produced of all API gravities.
Vp,q = Volume of oil produced, for well p in basin q, in barrels in the calendar year during which associated gas was vented or flared. x = Total number of wells in the basin that vent or flare associated gas.
(5) Calculate emissions from associated gas to flares as follows:
(l) Flare stack or other destruction device emissions. Calculate CO2, CH4 and N2O emissions from a flare stack or other destruction device as follows:
(3) If a continuous gas composition analyzer is not installed on gas or liquid supply to the flare or destruction device, use the appropriate gas composition for each stream of hydrocarbons going to the flare as follows:
(5) Calculate GHG volumetric emissions at actual conditions using Equations 18 and 19 of this section.
)
(Eq. 18)
)
(Eq. 19)
Where:
Ea,CH4 = Annual CH4 emissions from flare stack in cubic feet, under actual conditions.
Ea,CO2 = Annual CO2 emissions from flare stack in cubic feet, under actual conditions.
Va = Volume of gas sent to flare in cubic feet, during the year.
η = Fraction of gas combusted by a burning flare (default is 0.98). For gas sent to an unlit flare, η is zero.
XCH4 = Mole fraction of CH4 in gas to the flare.
ZL = Fraction of the feed gas sent to a burning flare (equal to 1 - ZU).
ZU = Fraction of the feed gas sent to an unlit flare determined by engineering estimate and process knowledge based on best available data and operating records.
XCO2 = Mole fraction of CO2 in gas to the flare.
Yj = Mole fraction of gas hydrocarbon constituents j (such as methane, ethane, propane, and pentanes-plus).
Rj = Number of carbon atoms in the gas hydrocarbon constituent j: 1 for methane, 2 for ethane, 3 for propane, 4 for butane, and 5 for pentanes-plus.
(m) Centrifugal compressor venting. Calculate CH4, CO2 and N2O (when flared) emissions from both wet seal and dry seal centrifugal compressor vents as follows:
(1) For each centrifugal compressor with a rated horsepower of 250hp or greater covered by sections 95152(c)(12), (d)(5), (e)(6), (f)(5), (g)(3), and (h)(3) the operator must conduct an annual measurement in each operating mode in which it is found for more than 200 hours in a calendar year. Measure emissions from all vents (including emissions manifolded to common vents) including wet seal oil degassing vents, unit isolation valve vents, and blowdown valve vents. Record emissions from the following vent types in the specified compressor modes during the annual measurement:
(A) Operating mode, blowdown valve leakage through the blowdown vent, wet seal and dry seal compressors. For all centrifugal compressor start-ups where natural gas is used as spin-up or starting gas (i.e. not combusted in the compressor), venting of this gas must be quantified and reported as follows:
)
(Eq. 20)
Where:
ESGi = Annual GHGi (CO2 and CH4) vented emissions at standard conditions in cubic feet.
n = number of compressor start-ups using spin gas.
Vsg = Volume of spin-up gas in standard cubic feet determined by metering or engineering estimates based on best available data.
CF = Fraction of spin-up gas that is sent to vapor recovery or fuel gas as determined by keeping logs of the number of operating hours for the vapor recovery system and the amount of gas that is directed to the fuel gas or vapor recovery system.
Yi = Mole fraction of GHGi in the vent gas.
Calculate both CH4 and CO2 mass emissions from volumetric emissions using calculations in paragraph (t) of this section.
(C) Not operating depressurized mode, unit isolation valve leakage through open blowdown vent, without blind flanges, wet seal and dry seal compressors.
(5) Estimate annual emissions using the flow measurement and Equation 21 of this section.
)
(Eq. 21)
Where:
Es,i,m = Annual GHG (either CH4 or CO2) volumetric emissions at standard conditions, in cubic feet.
MTm = Measured gas emissions in standard cubic feet per hour during operating mode m as described in sections (m)(1)(A) through (m)(1)(C).
Tm = Total time the compressor is in the mode for which Es,i is being calculated, in the calendar year in hours.
Yi = Mole fraction of GHGi in the vent gas.
CF = Fraction of centrifugal compressor vent gas that is sent to vapor recovery or fuel gas as determined by keeping logs of the number of operating hours for the vapor recovery system and the amount of gas that is directed to the fuel gas or vapor recovery system.
(6) For each centrifugal compressor with a rated horsepower of less than 250hp covered by sections 95152(c)(12), (d)(5), (e)(6), (f)(5), (g)(3), and (h)(3), the operator must calculate annual emissions from both wet seal and dry seal centrifugal compressor vents using Equation 22 of this section.
Es,i = Count * EFi
(Eq. 22)
Where:
Es,i = Annual total volumetric GHG emissions at standard conditions from centrifugal compressors (<250hp) in cubic feet.
Count = Total number of centrifugal compressors less than 250hp.
EFi = Emission factor for GHGi. Use 1.2 x 107 standard cubic feet per year per compressor for CH4 and 5.30 x 105 standard cubic feet per year per compressor for CO2 at 60°F and 14.7 psia.
(8) Calculate emissions from seal oil degassing vent vapors to flares as follows:
(n) Reciprocating compressor venting. Calculate CH4 and CO2, and N2O (when flared) emissions from all reciprocating compressor vents as follows:
(1) For each reciprocating compressor with a rated horsepower of 250hp or greater covered in sections 95152(c)(13), (d)(6), (e)(7), (f)(6), (g)(4), and (h)(4) the facility operator must conduct an annual measurement for each compressor in each operating mode in which it is found for more than 200 hours in a calendar year. Measure emissions from (including emissions manifolded to common vents) reciprocating rod packing vents, unit isolation valve vents, and blowdown valve vents. Record emissions from the following vent types in the specified compressor modes during the annual measurement as follows:
(C) Not operating depressurized mode, unit isolation valve leakage through the blowdown vent stack, without blind flanges.
(2) If reciprocating rod packing and blowdown vent are connected to an open-ended vent line, use one of the following two methods to calculate emissions:
(3) If reciprocating rod packing is not equipped with a vent line use the following method to calculate emissions:
(5) Estimate annual emissions using the flow measurement and Equation 23 of this section.
)
(Eq. 23)
Where:
Es,i,m = Annual GHGi (either CH4 or CO2) volumetric emissions, in standard cubic feet.
MTm = Measured gas emissions in standard cubic feet per hour during operating mode m as described in sections (n)(1)(A) through (n)(1)(C).
Tm = Total time the compressor is in the mode for which Es,i,m is being calculated, in the calendar year in hours.
Yi = Mole fraction of GHGi in the vent gas.
CF = Fraction of reciprocal compressor vent gas that is sent to vapor recovery or fuel gas as determined by keeping logs of the number of operating hours for the vapor recovery system and the amount of gas that is directed to the fuel gas or vapor recovery system.
(6) For each reciprocating compressors with a rated horsepower of less than 250hp, the operator must calculate annual emissions using Equation 24 of this section.
Es,i = Count * EFi
(Eq. 24)
Where:
Es,i = Annual total volumetric GHG emissions at standard conditions from reciprocating compressors in cubic feet.
Count = Total number of reciprocating compressors for the facility operator.
EFi = Emission factor for GHGi. Use 9.48 x 103 standard cubic feet per year per compressor for CH4 and 5.27 x 102 standard cubic feet per year per compressor for CO2 at 60°F and 14.7 psia.
(o) Leak detection and leaker emission factors. The operator must use the methods described in section 95154(a) to conduct leak detection(s) of equipment leaks from all components types listed in sections 95152(c)(16), (d)(7), (e)(8), (f)(7), (g)(5), (h)(5), and (i)(1). This paragraph (o) applies to component types in streams with gas content greater than 10 percent CH4 plus CO2 by weight. Component types in streams with gas content less than 10 percent CH4 plus CO2 by weight do not need to be reported. Tubing systems equal to or less than one half inch diameter are exempt from the requirements of this paragraph (o) and do not need to be reported. If equipment leaks are detected for sources listed in this paragraph (o), calculate equipment leak emissions per component type per reporting facility using Equations 25 or 26 of this section for each component type. Use Equation 25 for industry segments listed in section 95150(a)(1) - (a)(7). Use Equation 26 for natural gas distribution facilities as defined in section 95150(a)(8). Use methods found in section 95153(t) to convert GHGi volume emissions to GHGi mass emissions.
)
(Eq. 25)
)
(Eq. 26)
Where:
Es,i = Annual total volumetric GHG emissions at standard conditions from each component type in cubic feet, as specified in (o)(1) through (o)(8) of this section.
X = Total number of each component type.
EF = Leaker emission factor for specific component types listed in Table 1A and 2 through 7 of Appendix A.
GHGi = For onshore petroleum and natural gas production facilities, concentration of GHGi, CH4 or CO2, in produced natural gas as defined in paragraph (s)(2)(A) of this section; For onshore natural gas processing facilities, concentration of GHGi, CH4 or CO2, in the total hydrocarbon of the feed natural gas; for onshore natural gas transmission compression and underground natural gas storage, GHGi equals 0.975 for CH4 and 1.1 x 10-2 for CO2; for LNG storage and LNG import and export equipment, GHGi equals 1 for CH4 and 0 for CO2; and for natural gas distribution, GHGi equals 1 for CH4 and 1.1 x 10-2 for CO2 or use the experimentally determined gas composition for CO2 and CH4.
Tp = The total time the component, p, was found leaking and operational, in hours. If one leak detection survey is conducted, assume the component was leaking for the entire calendar year. If multiple leak detection surveys are conducted, assume that the component found to be leaking has been leaking since the previous survey (if not found leaking in the previous survey) or the beginning of the calendar year (if it was found leaking in the previous survey) or the beginning of the calendar year (if it was found leaking in the previous survey). For the last leak detection survey in the calendar year, assume that all leaking components continue to leak until the end of the calendar year.
t = Calendar year of reporting.
n = The number of years over which one complete cycle of leak detection is conducted over all the Transmission - Distribution (T-D) transfer stations in a natural gas distribution facility; 0 < n ≤ 5. For the first (n-1) calendar years of reporting the summation in Equation 26 should be for years that the data is available.
Tp,q = The total time the component, p, was found leaking and operational, in hours, in year q. If one leak detection survey is conducted, assume the component was leaking for the entire period n. If multiple leak detection surveys are conducted, assume the component found to be leaking has been leaking since the previous survey) or the beginning of the calendar year (if it was found to be leaking in the previous survey). For the last leak detection survey in the cycle, assume that all leaking components continue to leak until the end of the cycle.
(8) Natural gas distribution facilities for above ground transmission-distribution transfer stations, shall use the appropriate default leak emission factors listed in Table 7 of Appendix A for equipment leaks detected from connectors, block valves, control valves, pressure relief valves, orifice meters, regulators, and open ended lines. Leak detection at natural gas distribution facilities is only required at above grade stations that qualify as transmission-distribution transfer stations. Below grade transmission-distribution transfer stations and all metering-regulating stations that do meet the definition of transmission-distribution transfer stations are not required to perform component leak detection under this section.
(p) Population count and emission factors. This paragraph applies to emissions sources listed in sections 95152(c)(16), (f)(7), (g)(5), (h)(5), (i)(2), (i)(3), (i)(4), (i)(5), (i)(6), and (i)(10) on streams with gas content greater than 10 percent CH4 plus CO2 by weight. Emissions sources in streams with gas content less than 10 percent CH4 plus CO2 by weight do not need to be reported. Tubing systems equal to or less than one half inch diameter are exempt from the requirements of paragraph (p) of this section and do not need to be reported. Calculate emissions from all sources listed in this paragraph using Equation 27 of this section.
(2) Onshore petroleum and natural gas production facilities must use the appropriate default population emission factors listed in Table 1A of Appendix A for equipment leaks from valves, connectors, open ended lines, pressure relief valves, pump, flanges, and other. Major equipment and components associated with gas wells are considered gas service components in reference to Table 1A of Appendix A and major natural gas equipment in reference to Table 1B of Appendix A. Major equipment and components associated with crude oil wells are considered crude service components in reference to Table 1A of Appendix A and major crude oil equipment in reference to Table 1C of Appendix A. Where facilities conduct EOR operations the emissions factor listed in Table 1A of Appendix A shall be used to estimate all streams of gases, including recycle CO2 stream. The component count can be determined using either of the methodologies described in this paragraph (p)(2). The same methodology must be used for the entire calendar year.
(A) Component Count Methodology 1. For all onshore petroleum and natural gas production operations in the facility perform the following activities:
(6) Natural gas distribution facilities must use the appropriate emission factors as described in paragraph (p)(6) of this section.
(B) Emissions from all above grade metering-regulating stations (including above grade T-D transfer stations) must be calculated by applying the emission factor calculated in Equation 28 and the total count of metering/regulator runs at all above grade metering-regulating stations (inclusive of T-D transfer stations) to Equation 27. The facility wide emission factor in Equation 28 will be calculated by using the total volumetric GHG emissions at standard conditions for all equipment leak sources calculated in Equation 26 and the count of meter/regulator runs located at above grade transmission-distribution transfer stations that were monitored over the years that constitute one complete cycle as per (p)(1) of this section. A meter on a regulator run is considered one meter regulator run. Facility operators that do not have above grade T-D transfer stations shall report a count of above grade metering-regulating stations only and do not have to comply with section 95157(c)(16)(T).
EF = Es,i/(8760 * Count)
(Eq. 28)
Where:
EF = Facility emission factor for a meter/regulator run per component type at above grade meter/regulator run for GHGi in cubic feet per meter/regulator run per hour.
Es,i = Annual volumetric GHGi emissions, CO2 or CH4, at standard condition from each component type at all above grade T-D transfer stations, from Equation 26.
Count = Total number of meter/regulator runs at all T-D transfer stations that were monitored over the years that constitute one complete cycle as per paragraph (o)(8)(A) of this section.
8760 = Conversion to hourly emissions (use 8784 for a leap year).
Es,i = Counts * EFs * GHGi * Ts
(Eq. 27)
Where:
Es,i = Annual volumetric GHG emissions at standard conditions from each component type in cubic feet.
Counts = Total number of this type of emission source at the facility. Underground natural gas storage shall count the components listed for population emission factors in Table 4. LNG storage shall count the number of vapor recovery compressors. LNG import and export shall count the number of vapor recovery compressors. Natural gas distribution shall count the meter/regulator runs and the number of customer meters as described in paragraph (p)(6) of this section.
EFs = Population emission factor for the specific component type, as listed in Table 1A and Tables 3 through Table 7 of Appendix A. Use appropriate emission factor for operations in Western U.S., according to Table 1(A) - 1(C) of Appendix A. EF for meter/regulator runs at above grade metering-regulator stations is determined in Equation 28 of this section.
GHGi = For onshore petroleum and natural gas production facilities, concentration of GHGi, CH4 or CO2, in produced natural gas as defined in paragraph (s)(2) of this section; for onshore natural gas transmission compression and underground natural gas storage, GHGi equals 0.975 for CH4 and 1.1 x 10-2 for CO2; for LNG storage and LNG import and export equipment, GHGi equals 1 for CH4 and 0 for CO2; for natural gas distribution, GHGi equals 1 for CH4 and 1.1 x 10-2 for CO2 or use the experimentally determined gas composition for CO2 and CH4.
Ts = Total time that each component type associated with the equipment leak emission was operational in the calendar year, in hours, using engineering estimate based on best available data, assume Ts = 8760 hours (or 8784 hours for a leap year) for section 95152(i)(10).
(q) Offshore petroleum and natural gas production facilities. Operators must report CO2, CH4, and N2O emissions for offshore petroleum and natural gas production from all equipment leaks, vented emission, and flare emission source types as identified in the data collection and emissions estimate study (Year 2008 Gulfwide Emission Inventory Study (GOADS) (December 2010)) conducted by BOEMRE in compliance with 30 CFR §§ 250.302 through 304 (July 1, 2011), which is hereby incorporated by reference.
(1) Offshore production facilities under BOEMRE jurisdiction must report the same annual emissions as calculated and reported by BOEMRE in data collection and emissions estimate study published by BOEMRE and referenced in 30 CFR §§ 250.302 through 304 (July 1, 2011) Gulfwide Offshore Activities Data System (GOADS).
(2) Offshore production facilities that are not under BOEMRE jurisdiction must use monitoring methods and calculation methodologies published by BOEMRE and referenced in 30 CFR §§ 250.302 through 304 (July 1, 2011) to calculate and report emissions (GOADS).
(r) Volumetric emissions. If equation parameters in section 95153 are already at standard conditions, which results in volumetric emissions at standard conditions, then this paragraph does not apply. Calculate volumetric emissions at standard conditions as specified in paragraphs (r)(1) or (2) of this section, with actual pressure and temperature determined by engineering estimates based on best available data unless otherwise specified.
(1) Calculate natural gas volumetric emissions at standard conditions using actual natural gas emission temperature and pressure, and Equation 29 of this section.
Es,n = Ea,n * (459.67 + Ts) * Pa/((459.67 + Ta) * Ps)
(Eq. 29)
Where:
Es,n = Natural gas volumetric emissions at standard temperature and pressure (STP) conditions in cubic feet except Es,n equals (FRs,p) for each well p, when calculating either subsonic or sonic flow rates under section 95153(f).
Ea,n = Natural gas volumetric emissions at actual conditions in cubic feet.
Ts = Temperature at standard conditions (60°F).
Ta = Temperature at actual conditions (°F).
Ps = Absolute pressure at standard conditions (14.7 psia).
Pa = Absolute pressure at actual conditions (psia).
(2) Calculate GHG volumetric emissions at standard conditions using actual GHG emissions temperature and pressure, and Equation 30 of this section.
Es,i = Ea,i * (459.67 + Ts) * Pa/((459.67 + Ta) * Ps)
(Eq. 30)
Where:
Es,i = GHG i volumetric emissions at standard conditions in cubic feet.
Ea,i = GHG i volumetric emissions at actual conditions in cubic feet.
Ts = Temperature at standard conditions (60°F).
Ps = Absolute pressure at standard conditions (14.7 psia).
Pa = Absolute pressure at actual conditions (Psia).
(s) GHG volumetric emissions. Calculate GHG volumetric emissions at standard conditions as specified in paragraphs (s)(1) and (s)(2) of this section, with mole fraction of GHGs in the natural gas determined by engineering estimate based on best available data unless otherwise specified.
(1) Estimate CH4 and CO2 emissions from natural gas emissions using Equation 31 of this section.
Es,i = Es,n * Mi
(Eq. 31)
Where:
Es,i = GHG i (either CH4 or CO2) volumetric emissions at standard conditions in cubic feet.
Es,n = Natural gas volumetric emissions at standard conditions in cubic feet.
Mi = Mole fraction of GHG i in the natural gas.
(2) For Equation 31 of this section, the mole fraction, Mi, must be the annual average mole fraction for each basin or facility, as specified in paragraphs (s)(2)(A) through (s)(2)(G) of this section.
(t) GHG mass emissions. Calculate GHG mass emissions by converting the GHG volumetric emissions at standard conditions into mass emissions using Equation 32 of this section.
Massi = Es,i * ρi* 10-3
(Eq. 32)
Where:
Massi = GHGi (either CH4, CO2, or N2O) mass emissions in metric tons GHGi.
Es,i = GHGi (either CH4, CO2, or N2O) volumetric emissions at standard conditions, in cubic feet.
Pi = Density of GHGi. Use 0.0526 kg/ft3 for CO2 and N2O, and 0.0192 kg/ft3 for CH4 at 60°F and 14.7 psia.
(u) EOR injection pump blowdown. Calculate CO2 pump blowdown emissions from EOR operations using critical CO2 injection as follows:
MassCO2 = N * Vv * Rc * GHGi * 10-3
(Eq. 33)
Where:
MassCO2 = Annual EOR injection gas venting emissions in metric tons from blowdowns.
N = Number of blowdowns for the equipment in the calendar year.
Rc = Density of critical phase EOR injection gas in kg/ft3. The facility operator may use an appropriate standard method published by published by a consensus based organization if such a method exists or the facility operator may use an industry standard practice to determine density of super-critical emissions.
Vv = Total volume in cubic feet of blowdown equipment chambers (including pipelines, manifolds and vessels) between isolation valves.
GHGi = Mass fraction of GHGi in critical phase injection gas.
1x 10-3 = Conversion factor from kilograms to metric tons.
(v) Crude Oil, Condensate, and Produced Water Dissolved CO2 and CH4. The operator must calculate dissolved CO2 and CH4 in crude oil, condensate, and produced water. This reporting requirement includes emissions from hydrocarbon liquids and water produced using EOR operations. Emissions must be reported for crude oil, condensate, and produced water sent to storage tanks, ponds, and holding facilities. The facility operator must also report the volume of produced water in barrels per year.
(1) Calculate CO2 and CH4 emissions from crude oil, condensate, and produced water using Equation 33A:
(A) S (the mass of CO2 or CH4 per barrel of crude oil, condensate, or produced water) shall be determined using one of the following methods:
2. Vapor recovery system method. For storage tank systems connected to a vapor recovery system, calculate the mass of CO2 and CH4 liberated from crude oil, condensate, or produced water as follows:
ECO2/CH4 = (S * V)(1 - (VR * CE))
(Eq. 33A)
Where:
ECO2/CH4 = Annual CO2 or CH4 emissions in metric tons.
S = Mass of CO2 or CH4 liberated in a flash liberation test per barrel of crude oil, condensate, and produced water (as determined in paragraph (v)(1)(A)1. or mass of CO2 or CH4 recovered in a vapor recovery system per barrel of crude oil, condensate, or produced water (as determined in paragraph (v)(1)(A)2.
V = Barrels of crude oil, condensate, or produced water sent to tanks, ponds, or holding facilities annually.
VR = Percentage of time the vapor recovery unit was operational (expressed as a decimal).
CE = Collection efficiency of the vapor recovery system (expressed as a decimal).
(y) Onshore petroleum and natural gas production and natural gas distribution combustion emissions. Calculate CO2, CH4, and N2O combustion-related emissions from stationary or portable equipment, except as specified in paragraph (y)(3) and (y)(4) of this section as follows:
(1) If a fuel combusted in the stationary or portable equipment is listed in Table C-1 of Subpart C of 40 CFR Part 98, or is a blend completely consisting of one or more fuels listed in Table C-1, calculate emissions according to paragraph (y)(1)(A). If the fuel combusted is natural gas and is of pipeline quality specification, use the calculation methodology described in paragraph (y)(1)(A) and the facility operator may use the emission factor provided for natural gas as listed in Subpart C, Table C-1. If the fuel is natural gas, and is not pipeline quality calculate emissions according to paragraph (y)(2). The operator must use the appropriate gas composition for each stream of hydrocarbon going to the combustion unit as specified in paragraph (s)(2) of this section. If the fuel is field gas, process vent gas, or a blend containing field gas or process vent gas, calculate emissions according to paragraph (y)(2).
(2) For fuel combustion units that combust field gas, process vent gas, a blend containing field gas or process vent gas, or natural gas that is not of pipeline quality, calculate combustion emissions as specified below:
(C) Calculate GHG volumetric emissions at actual conditions using Equations 35 and 36 of this section:
)
(Eq. 35)
)
(Eq. 36)
Where:
Ea,CO2 = Contribution of annual CO2 emissions from portable or stationary fuel combustion sources in cubic feet, under actual conditions.
Va = Volume of fuel gas sent to combustion unit in cubic feet, during the month.
YCO2 = Monthly concentration of CO2 constituent in gas sent to combustion unit.
Ea,CH4 = Contribution of annual CH4 emissions from portable or stationary fuel combustion sources in cubic feet, under actual conditions.
η= Fraction of gas combusted for portable and stationary equipment. A default value of 0.995 can be used for all internal and external combustion devices. The operator may use an alternative engineering estimation value based on chemical analysis data, equipment-specific specifications, or industry standard references demonstrating the combustion efficiency of the unit type (e.g. boiler, heater, etc.).
Yj = Monthly concentration of gas hydrocarbon constituent j (such as methane, ethane, propane, butane and pentanes plus) in gas sent to combustion unit.
Rj = Number of carbon atoms in the gas hydrocarbon constituent j; 1 for methane, 2 for ethane, 3 for propane, 4 for butane, and 5 for pentanes plus, in gas sent to combustion unit.
YCH4 = Monthly concentration of methane constituent in gas sent to combustion unit.
n = Month of the year
Calculate CO2 and CH4, volumetric emissions at standard conditions using the provisions of section 95153(r). Use the provisions in sections 95153(s) and (t) to convert volumetric gas emissions to GHG volumetric and GHG mass emissions respectively.
(D) Calculate N2O mass emissions using Equation 37 of this section.
MassN2O = (1 x 10-3) * Fuel * HHV * EF
(Eq. 37)
Where:
MassN2O = Annual N2O emissions from the combustion of a particular type of fuel (metric tons N2O).
Fuel = Mass or volume of the fuel combusted (mass or volume per year, choose appropriately to be consistent with the units of HHV).
HHV = For the higher heating value for field gas or process vent gas, use either a weighted average of measurements of HHV or a default value of 1.235 x 10-3 MMBtu/scf for HHV. Samples must be collected once during each three-month period of the calendar year, with at least 30 days between successive samples.
EF = Use 1.0 x 10-4 kg N2O/MMBtu.
1 x 10-3 = Conversion factor from kilograms to metric tons.
The operator of a facility must calculate and report annual GHG emissions as prescribed in this section. The facility operator who is a local distribution company reporting under section 95122 of this article must comply with section 95153 for reporting emissions from the applicable source types in section 95152(i) of this article.
Note: Authority cited: Sections 38510, 38530, 39600, 39601, 39607, 39607.4 and 41511, Health and Safety Code. Reference: Sections 38530, 39600 and 41511, Health and Safety Code.
1. New section filed 12-14-2011; operative 1-1-2012 pursuant to Government Code section 11343.4 (Register 2011, No. 50).
2. Repealer and new section filed 12-19-2012; operative 1-1-2013 pursuant to Government Code section 11343.4 (Register 2012, No. 51).
3. Redesignation of subsections (c)(7)1.-3. as subsections (c)(7)(A)-(C), amendment of subsections (f), (f)(1) and (k)(2)(A), redesignation of subsection (m)(1)(D) as subsection (m)(1)(C)2. and amendment of subsections (m)(3), (o), (o)(8)(A), (p), (p)(6)(B), (u), (v) and (v)(1)(A)1., new subsection (v)(1)(A)2.e. and amendment of subsections (y)(1)-(4) filed 12-31-2013; operative 1-1-2014 pursuant to Government Code section 11343.4(b)(3) (Register 2014, No. 1).
4. Amendment filed 12-31-2014; operative 1-1-2015 pursuant to Government Code section 11343.4(b)(3) (Register 2015, No. 1).
5. Amendment filed 9-1-2017; operative 1-1-2018 (Register 2017, No. 35).
6. Amendment of subsections (b), (p) and (p)(6)(B) filed 3-29-2019; operative 4-1-2019 pursuant to Government Code section 11343.4(b)(3) (Register 2019, No. 13).