58 F. 387 | U.S. Circuit Court for the District of Massachusetts | 1893
The Brush patent Bo. 337,299 for improvements in secondary batteries has been sustained by the courts in several cases. Electrical Accumulator Co. v. Julien Electric Co., 38 Fed. Rep. 117; Brush Electric Co. v. Julien Electric Co., 41 Fed. Rep. 679; Brush Electric Co. v. Electrical Accumulator Co., 47 Fed. Rep. 48; Id., 1 U. S. App. 320, 2 C. C. A. 682, 52 Fed. Rep. 130; Brush Electric Co. v. Accumulator Co., 50 Fed. Rep. 833. Belying on these prior adjudications, the plaintiffs now ask for a preliminary injunction against the defendants. In opposing this motion the defendants do not attack the validity of the Brush patent, but rest their defense on noninfringement. The question, therefore, presented by this motion is whether the defendants’ battery is within the Brush patent.
It may be observed at the outset that, while Brush' has taken out a number of patents relating to secondary batteries,- the patent in suit is for his broad invention. In the contest between Brush and Faure as to which was entitled to claim this broad invention it was decided that Brush was an original inventor, and the first in this country.
To pass intelligently upon the question of infringement raised by this motion we must first understand what the Brush invention is, and the position it occupies in the art. In this inquiry I shall adopt the conclusions reached by the courts of the second circuit in the cases already cited. A secondary battery is a battery which has no original power of developing a current of electricity, and is active only when rendered so by sending a current elsewhere generated through it. When such a battery is charged from an outside source, as from a dynamo machine, it becomes capable of giving back a current due to the energy which has been stored in it. A primary battery is a chemical generator of electricity, which is active only by virtue of the materials of which it is composed. “The two differ as a spring differs from a reservoir,” as was aptly said by Judge Coxe in the first Julien Case. In a secondary battery the electrodes are of the same -materials, and electro-motively similar, and the plates are insoluble in the battery fluid. In a primary battery the electrodes are of different materials, and differ electro-motively, and the positive plate is dissolved in the battery fluid. The capacity of a primary battery to give a current is limited, and it is soon exhausted, while in a secondary
Gaston Plante, about 1860, first gave to the world a practical secondary or storage battery. Plante took two thin sheets of lead, immersed them in an electrolyte of dilute sulphuric acid, connected them respectively with two poles of any suitable source of electricity, and passed a current through them. This developed oxygen on one lead plate and hydrogen on the other. The hydrogen passed off in bubbles, leaving the plate practically unaffected; but the oxygen combined chemically with the lead of the other plate, and formed a film or skin of peroxide of lead of a finely divided granular character. This coating of peroxide operating to protect the underlying lead soon stopped the action of the oxygen on the lead. The current was then stopped. It was found that the two plates, one covered with a thin film of peroxide of lead, and the other consisting of metallic lead, were capable of discharging a minute quantity of current. This power of discharge was lost if the plates were allowed to stand any time before discharge, and was too small to be of any practical value. Upon investigating these phenomena, Plante discovered that this loss of discharging power was due to local action between the peroxide film and tin; underlying metallic lead of the plate, whereby the oxygen, by corroding more of the plate, added to the thickness of the film, which now became not peroxide, but a lower oxide. He also discovered that a thicker film on one plate was useless without then; was a corresponding film of equal thickness on the other plate. In order, therefore, to produce the granular or spongy film on the other plate, he conceived the idea of reversing the current of the change, which resulted in developing oxygen on the former hydrogen plate, thereby producing a layer of peroxide on its surface, and hydrogen on the former oxygen plate, which robbed tbe oxide film of its oxygen, and left it metallic lead, but granular or spongy in physical structure. This second charge was continued as long as the first, followed, as before, by a period of rest. Then a third charge followed in the same direction as the first, and another period of rest; and so on, charge, rest, and reversal followed charge, rest, and reversal for days and weeks, the charges gradually increasing in length as the layers increased in thickness. These layers constituted the active material of the battery, and they were formed by a disintegration of the surface of the solid lead plate through electrical action. It took weeks or months before a layer of
. Having investigated the Plante battery, Brush conceived the idea of taking a quantity of oxide of lead or active material and applying it directly to the lead plates before immersion in the battery fluid. This dispensed with the tedious process of “forming” such coatings out of the substance of the plate by electrical treatment, and also provided a larger quantity of active .material than was practicable under the Plante method. In his patent ■ Brush declares that his invention consists in a secondary battery element or electrode composed of a suitable plate or support, primarily coated or combined with active material, and in the method of constructing such electrodes by mechanically coating or combining suitable plates or supports with active material. The patent describes the plates as plain, corrugated, ribbed, honeycombed, or studded. They may have grooves or depressions or slots or perforations extending through the plate. The oxide of lead or active material may be retained in position on the plate by a sheet of heavy paper or equivalent substance, secured to the plate in any suitable manner by rivets or binding strips, or the lead oxide may be spread on the plate, and made to adhere by applying pressure. When a pair of these plates are associated together to form a secondary battery, and immersed in dilute sulphuric acid, and charged by the passage of an electric current in the usual manner, one of the plates has its coating peroxidized and forms the oxygen element of the battery, while the other plate has its coating of oxygen reduced to the metallic state, and then absorbs hydrogen, and so forms the hydrogen element of the battery.
The specification then declares:
"I would, nave it understood that' I do not restrict myself to any particular form of active or absorptive material, or to any particular me'hod of applying it to or combining it with the plate or support, as my invention consists, broadly, in a secondary battery plate or element having active or absorptive material primarily and mechanically applied thereto or combined therewith, as contradistinguished from a plate of element having the active material produced by the disintegrating action of electricity, as in the well-known Plante process.”
This patent is for the broad invention of Brush. It consists of a secondary battery electrode in which the active material is mechanically applied to a support plate. It was an improvement •of the PJante method. It starts, as Plante did, with the plate; but instead of obtaining the active material from the disintegration of the plate itself by the slow process of forming, Brush purchased the active material, and applied it directly to the plate. He provided three ways in which this could be done. If a. plain plate is used, the active material may be held in place by a sheet of porous nonconducting material, like blotting paper. If a re-ceptaeled plate is used, the active material may be rammed or
It has been held in the prior adjudications on this patent that batteries of the primary type are not anticipations of Brush, because the twro classes of batteries are different in construction, mode of operation, and result. It has also been held that secondary batteries of the vessel-support type like the Percival do not anticipate Brush, for the reason that they have no support plate; the very purpose of that type of battery being to do away with every form of supporting plate. It has further been decided that this invention is not anticipated by (.he Brush Italian patent, because, among other reasons, the plates described in that patent were specially prepared for the purpose of more rapidly forming active material thereon by the Plante method of disintegration. The invention of Brush is thus described by Judge Ooxe:
“Air. Brush was the first in this country to hold absorptive substance, in the form of dry powder, in place on Hie supports of a secondary battery by paper or equivalent. material, and the fiist who rammed or pressed it into grooves or receptacles in the plates.” Brush Electric Co. v. Electrical Accumulator Co., 47 Fed. Rep. 48, 49.
But, while holding (hat Brush was entitled to this broad invention, it was decided that certain specific constructions belonged to others; that Faure was the first inventor of the application, of the active material in the form of paste, paint, or cement, and that Brush was not the first to make the plate with perforations extending through it.
It is necessary now to examine defendants’ battery, and to determine whether it contains the Brush 'invention. The Usher battery, used by defendants, consists of a plate in the form of a rectangular frame or grid, with vertical and horizontal ribs. Inclosed and bold between the ribs are packages of active material, having a wrapping of thin sheet lead. The wrapping is perforated, and the perforations filled with gum. The packages are filled with active material in the form of powdered oxide of lead, commercially known as red lead. Thin sheets of kiln-dried wood separate the plates. The plates and sheets are held together by rubber bands, and are set in a receptacle of hard rubber containing dilute sulphuric acid. In structure, certainly, this battery appears to have the elements of the Brush invention,- — a support plate combined with mechanically applied active material, the plates being separated by sheets of porous nonconducting material. It is insisted, however, by defendants that the plate of the Usher battery is not a support plate; but why, it is difficult to see. It certainly acts as a support for the' active material. When the packages of red lead are inserted in
Again, the Usher plates are separated by sheets of porous material in the form of kiln-dried wood. These sheets help to support the active material upon the plates, just as the sheets of porous blotting paper in the Brush battery. Brush does not confine the use of tMs porous medium to plain plates, but specifically states that it may be used with receptacled plates. The fact that the Brush battery of commerce is constructed without this porous medium, and that this is considered an inferior form of construction, does not make it any. less a part of the- Brash invention, , - In the Brush battery, as ordinarily constructed, the active material is applied to the plate by pressure. This leads the defendants to declare that the Brush invention is limited to the use of some kind of pressure,, and that Usher does not use any pressure. A glance at the Brush patent shows the unsoundness of this contention. He states in his patent that the active material may be applied to the plates in two ways, — * by interposing a sheet of porous material between the plates, or by spreading a quantity of material upon the plate and applying pressure, in which case no porous medium is necessary.
It is further urged by defendants that the active material of the Usher battery is new, and unknown before, and that it is not the active' material of the Brush battery. They assert that the oxide of lead 'in the Usher battery does not become the active material of the battery until it has passed through their forming or charging process, when it develops into a new and powerful peroxide. This is the only way they can account for the superior efficiency of the Usher battery. The answer of this is that when the defendants take a quantity of finely divided oxide of lead,-such as Plante produced by the disintegration of the plate, and wMch is known and understood in the art as “active material,” and apply it directly to a supporting plate, .to form the .electrode of a secondary battery, they have ap
There is little force ‘in the argument of defendants that the Usher battery belongs to the vessel-support type like the Percival battery, and is, therefore, not within the Brush patent, because it is apparent on inspection that it does not belong to that class. The distinguishing feature which marks the difference between the two classes of batteries is tlie support plate. In the Percival there is no support plate, either plain, perforated, or skeleton, but the active; material is placed in a vessel divided into two parts by a porous nonconducting partition. In the Usher battery there is clearly a support plate carrying the active material. Usher starts with a' plate, not a vessel, for the support of his active material, just the same as Plante and Brush. This feature removes the Usher battery from the vessel-support type, and it becomes a plate-support battery of the same type as Brush. The I)e la Rive battery described in the Electrician in the year 1863 was of the vessel-support type. The Usher battery is not a development of this type. Usher built upon Plante and Brush, not upon Percival or De la Rive. Nor is the Usher battery allied to the Brush Italian patent, for the same reasons that the Italian patent ivas held by the courts of the second circuit not to contain the invention covered hv the patent in suit.
I And, therefore, in the construction of the Usher battery, the combination in a secondary battery of a support plate, porous medium, and active material mechanically applied to the plate. This is the Brush invention. The special form of the plate, and the lead foil wrappings about the active material, may be new With Usher, but at the same time this battery contains all the features of the Brush invention.
But it is strenuously urged by defendants that the mode of operation of the Usher battery is radically different from Brush. They say that the Brush battery is an improvement on Plante, and that the improvement consists in getting rid of the forming process. They contend that their electrodes are “formed,” and that, therefore, they do not use the Brash process. I am unable to
It is also urged that the Usher battery produces new and useful results. One of these results is that it avoids injurious sulphation. Where sulphuric acid is the battery fluid, there will be more or less formation of sulphate of lead, due to local action. This sulphation tends to destroy the life of the battery, and causes the active material to fall away from the plates. Assuming that this evil exists to a less extent in the Usher battery only shows that Usher may have improved upon Brush, but it does not prove ,that the Brush invention is absent from the Usher structure.
And the same reply may be made to the alleged greater efficiency of the Usher battery. This is no answer to the charge of infringement, if it is clear that Usher has incorporated into his battery the Brush invention. I am not fully convinced of the great superiority of the Usher battery. If, as contended by the defendants, it has solved the problem of a practical storage battery for tramways, (a field in which it is said the Brush battery has only met with failure,) it seems strange that such an important discovery, worth, we are told, many millions of dollars, should not have become more widely known, and put into operation on a more extensive scale.
As to the Johnson battery, it is sufficient to say that, if the Usher battery infringes Brush, the same must be true of Johnson. The defendants have given up the use of the Johnson battery, and the only real contest on this motion has been upon the Usher battery.
I do. not think it necessary to consider at length the prior invention of Dr. Blanchard, introduced by the defendants for the purpose of limiting the broad claims of the Brush patent, rather than as an anticipation. It may be observed, however, that the Blanchard invention ' relates to a battery of the primary type; that it never served any practical purpose, and seems to have been soon abandoned. It further appears that this evidence was
“(1) A secondary battery dement or electrode consisting of a plate or suitable support primarily coated or combined with mechanically applied active material, or material adapted to become active, substantially as set forth”
Claim 2 sets forth a secondary battery electrode whose support is provided with a coating or surface layer of absorptive substance, such as metallic oxide, winch is applied thereto. Claim 3 specifies the active material as oxide of lead or equivalent lead compound. Claim 6 is as follows:
'•(0) A plate of suitable support provided with grooves, x)erforations, or receptacles, and primarily coated, combined, or tilled with mechanically, applied active material, or material adapted to become active, substantially as set forth.”
Claim 7 limits the active material applied to the grooves or perforations of the plate to oxide of lead or equivalent lead compound. Claim 9 is as follows:
•‘(9) The combination, with the plate or support of an electrode and an active spongy layer thereon, of a porous medium for holding said layer on the plate or support of the electrode, substantially as set forth.” ,,
Claim 10 includes as an element the fastening together of the support with its active material and holding medium. Claim 12 is as follows:
“The method of making plates or electrodes for secondary batteries, consisting in primarily combining active material with suitable plates or supports mechanically, in contradistinction to forming the active material by an electrical disintegration of the plate or support, substantially as set forth.”
I am of opinion for the reasons given that the defendants’ battery infringes these claims of the Brush patent, and that an injunction should be granted.